台湾中正大学高分子流变学课件.pptVIP

Topics in Each Section §2-1 Rheometry Shear and Shearfree Flows Flow Geometries Viscometric Functions §2-2 Basic Vector/Tensor Manipulations Vector Operations Tensor Operations §2-3 Material Functions in Simple Shear Flows Steady Flows Unsteady Flows §2-4 Material Functions in Elongational Flows 2.1. Rheometry Two standard kinds of flows, shear and shearfree, are used to characterize polymeric liquids The Stress Tensor Classification of Flow Geometries Typical Shear/Elongation Rate Range Concentration Regimes for Each Geometries Viscometric Functions Assumptions Flow Instability in a Concentric Cylinder Viscometer for a Newtonian Liquid Supplementary Examples Capillary: Example 10.2-3: Obtaining the Non-Newtonian Viscosity from the Capillary Concentric Cylinders Problem 10B.5: Viscous Heating in a Concentric Cylinder Viscometer Parallel Plates: Example 10.2-2: Measurement of the Viscometric Functions in the Parallel-Disk Instrument Problem 1B.5: Parallel-Disk Viscometer Problem 1D.2: Viscous Heating in Oscillatory Flow 2.2. Basic Vector/Tensor Manipulations Vector Operations (Gibbs Notation) Tensor Operations 2.3. Material Functions in Simple Shear Flows Remarks: A variety of experiments performed on a polymeric liquid will yield a host of material functions that depend on shear rate, frequency, time, and so on Representative fluid behavior will also be shown by means of sample experimental data The description of the nature and diversity of material response to simple shearing and shearfree flow is given Steady Shear Flow Material Functions Unsteady Shear Flow Material Functions 2.4. Material Functions in Elongational Flows Shearfree Flow Material Functions The number average and weight average molecular weights of the samples: Monodisperse, but with a tail in high M.W. (GPC results) * * Chapter II  Mechanical Characterizations *Most of figures appearing in this file are taken from the textbook “Dynamics of Polymeric Liquids” (Vol. 1). For