【2017年整理】镁合金表面磷酸盐转化膜研究.pdfVIP

1 1 1 1 2 , , , , ( 1重庆科技学院冶金与材料工程学院, 重庆 400050; 2重庆大学 材料科学与工程学院, 重庆 400045) : Zn(H PO ) AZ31AZ61 2 4 2 , X , , , , [ Zn ( PO ) 3 4 2 4H O ] [ Zn M g( PO ) 4H O] , 1, 3% 360 h, 2 2 4 2 2 144 h : ; ; ; ; :TG174. 46 :A 2007 Investigation onPhosphateFilms on the agnesium AlloysSurface 1 1 1 1 2 LAN W e i, ZH OU Anuo , SUN J ianchun , CA IW e i, ZHANG D ingfe i ( 1Schoo l ofM e tallu gy and M ate ia ls Eng inee ing, Chongq ing Un ive sity of Sc ience and T echnology, Chongqing 400050, China; 2Co llege ofM ate ials Sc ience and Eng inee ing, Chongqing Unive sity, Chongqing 400045, Ch ina) Abstract:T he so lut ion w h ich m ainly conta ined Zn(H PO ) w as used to p epa e phosphate film s on AZ31 and AZ61 2 4 2 m agnesium a lloys su face. T h ough o thogona l tests, the p ocess pa am ete s and the solution com position w as defined. T he m ic ost uctu e and com posit ions of the phosphate film s w e e analyzed by optical m ic oscope, SEM, spect um and XRD. The an tico osion ab ility of the film s was esea ched by NSS and som e o the m ethods. T he possible conve sion p ocess of the phosphate eact ions and antico osion m echanism of the f ilm sw e e d iscussed. The esults show that the c ystals of the conve sion film s is ve y f ine, and the m ajo com position of the film s is [ Zn ( PO ) 4H O] [ Zn M g( PO ) 4H O] . T he