利用触媒燃烧法处理冷凝后油气之研究.pdfVIP

利用觸媒燃燒法處理冷凝後油氣之研究 1 2 2 2 薛仲娟 何毓珊 許詩典 陳枋萱 2 2 2 2 魏思怡 佘尚樺 連奕婷 張章堂 1.國立宜蘭技術學院化學工程科 2.國立宜蘭技術學院環境工程系 摘 要 觸媒燃燒試驗是將有機溶劑蒸氣與空氣混合，經加熱器加熱後，達一定的處理 溫度，經觸媒床的觸媒氧化，然後經三種油氣所需處理溫度由低至高依序為 92 無鉛汽油油氣、95 無鉛汽油油氣、高級汽油油氣。管道排至抽氣櫃，整理各條 件處理溫度與出口濃度之關係，由實驗得知，未經冷凝各種油氣處理效率隨溫 度提高而加大；經冷凝後各種油氣處理效率達 90﹪ ，處理溫度隨濃度提高而加 大；相同的入流濃度下三種油氣所需處理溫度由低至高順序為92 無鉛汽油油 氣、 95 無鉛汽油油氣、高級汽油油氣。冷凝回收後由於低分子所占的比例較 高，因此較容易分解，所以處理溫度會降低。為有效回收油氣，一般乃冷凝之 後，再予以處理，因此本研究將評估各種冷凝溫度之觸媒處理特性與最佳操作 條件。 關鍵詞：觸媒燃燒，油氣，處理溫度，處理效率 Study on the Treatment of Gasoline Station VOCs with Catalytic Combustion Chung-Jeng Shay1 Yu-San Ho2 Shing-Teng Shu2 Feng-Sham Chen2 Shing-I Wen2 Sun-Hwa So2 I-Ting Len2 Chang-Tang Chang2 1. Department of Chemical Engineering, National Ilan Institute of Technology 2.Department of Environmental Engineering, National Ilan Institute of Technology Abstract The concentrations of VOCs emitted from gasoline station are high and harmful to human-being. It is benefit to recover the VOCs with recovery system. However, the flue gas of the recovery system is usually emitted to atmosphere directly. It is necessary to treat the fugitive VOCs to avoid pollution. Generally, the adsorption beds, absorption scrubbers, condensate system, and incinerators are able to control the waste gas. In this study, we use catalytic incinerator to evaluate the performance since it has the economic and high-efficiency characteristics. There are three kinds of gasoline used in our test, comprising of leaded, 92 unleaded, and 95 unleaded gasoline. Seven different temperat