multiblock copolymers of styrene and butyl acrylate via polytrithiocarbonate-mediated raft polymerization通过polytrithiocarbonate-mediated筏多次拉丝共聚物苯乙烯和丙烯酸丁酯的聚合.pdfVIP

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multiblock copolymers of styrene and butyl acrylate via polytrithiocarbonate-mediated raft polymerization通过polytrithiocarbonate-mediated筏多次拉丝共聚物苯乙烯和丙烯酸丁酯的聚合.pdf

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multiblock copolymers of styrene and butyl acrylate via polytrithiocarbonate-mediated raft polymerization通过polytrithiocarbonate-mediated筏多次拉丝共聚物苯乙烯和丙烯酸丁酯的聚合

Polymers 2011, 3, 719-739; doi:10.3390/polym3020719 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Multiblock Copolymers of Styrene and Butyl Acrylate via Polytrithiocarbonate-Mediated RAFT Polymerization Bastian Ebeling and Philipp Vana ¨ ¨ ¨ Institut fur Physikalische Chemie, Georg-August-Universitat Gottingen, Tammannstraße 6, D-37077 ¨ Gottingen, Germany Author to whom correspondence should be addressed; E-Mail: pvana@uni-goettingen.de; Tel.: +49-551-39-12753; Fax: +49-551-39-3144. Received: 18 February 2011; in revised form: 18 March 2011 / Accepted: 28 March 2011 / Published: 31 March 2011 Abstract: When linear polytrithiocarbonates as Reversible Addition-Fragmentation chain Transfer (RAFT) agents are employed in a radical polymerization, the resulting macromolecules consist of several homogeneous polymer blocks, interconnected by the functional groups of the respective RAFT agent. Via a second polymerization with another monomer, multiblock copolymers—polymers with alternating segments of both monomers—can be prepared. This strategy was examined mechanistically in detail based on subsequent RAFT polymerizations of styrene and butyl acrylate. Size-exclusion chromatography (SEC) of these polymers showed that the examined method yields low-disperse products. In some cases, resolved peaks for molecules with different numb