phosphane-based cyclodextrins as mass transfer agents and ligands for aqueous organometallic catalysisphosphane-based环糊精作为水的传质代理和配体有机金属催化.pdfVIP

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phosphane-based cyclodextrins as mass transfer agents and ligands for aqueous organometallic catalysisphosphane-based环糊精作为水的传质代理和配体有机金属催化.pdf

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phosphane-based cyclodextrins as mass transfer agents and ligands for aqueous organometallic catalysisphosphane-based环糊精作为水的传质代理和配体有机金属催化

Molecules 2012, 17, 13062-13072; doi:10.3390/molecules171113062 OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Review Phosphane-Based Cyclodextrins as Mass Transfer Agents and Ligands for Aqueous Organometallic Catalysis Sébastien Tilloy, Cécile Binkowski-Machut, Stéphane Menuel, Hervé Bricout and Eric Monflier * Unité de Catalyse et de Chimie du Solide (UCCS), CNRS, UMR 8181, Univ. Artois, Rue Jean Souvraz, SP 18, F-62307 Lens, France; E-Mails: sebastien.tilloy@univ-artois.fr (S.T.); cecile.machut@univ-artois.fr (C.B.-M.); stephane.menuel@univ-artois.fr (S.M.); herve.bricout@univ-artois.fr (H.B.) * Author to whom correspondence should be addressed; E-Mail: eric.monflier@univ-artois.fr; Tel.: +33-321-791-772; Fax: +33-321-791-755. Received: 11 October 2012; in revised form: 30 October 2012 / Accepted: 30 October 2012 / Published: 2 November 2012 Abstract: The replacement of hazardous solvents and the utilization of catalytic processes are two key points of the green chemistry movement, so aqueous organometallic catalytic processes are of great interest in this context. Nevertheless, these processes require not only the use of water-soluble ligands such as phosphanes to solubilise the transition metals in water, but also the use of mass transfer agents to increase the solubility of organic substrates in water. In this context, phosphanes based on a cyclodextrin skeleton are an interesting alternative since these compounds can simultaneousl