preparation of a porous composite film for the fabrication of a hydrogen peroxide sensor制备多孔复合膜的过氧化氢传感器的制造.pdfVIP

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preparation of a porous composite film for the fabrication of a hydrogen peroxide sensor制备多孔复合膜的过氧化氢传感器的制造.pdf

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preparation of a porous composite film for the fabrication of a hydrogen peroxide sensor制备多孔复合膜的过氧化氢传感器的制造

Sensors 2011, 11, 5873-5885; doi:10.3390/s110605873 OPEN ACCESS sensors ISSN 1424-8220 /journal/sensors Article Preparation of a Porous Composite Film for the Fabrication of a Hydrogen Peroxide Sensor Mu-Yi Hua 1,2,*, Chun-Jen Chen 1,2, Hsiao-Chien Chen 1,2, Rung-Ywan Tsai 3, Wen Cheng 4, Chun-Lin Cheng 4 and Yin-Chih Liu 1,2 1 Green Technology Research Center, Department of Chemical and Materials Engineering, Chang Gung University, Tao-Yuan 33302, Taiwan; E-Mails: d9023006@ (C.-J.C.); chainjim@.tw (H.-C.C.); jordan9090@.tw (Y.-C.L.) 2 Biosensor Group, Biomedical Engineering Research Center, Chang Gung University, Tao-Yuan 33302, Taiwan 3 Electronics and Optoelectronics Research Laboratories, Industrial Technology Research Institute, Hsinchu 31040, Taiwan; E-Mail: ry_tsai@.tw 4 Department of Chemical Engineering, Chung Yuan University, Tao-Yuan 33023, Taiwan; E-Mails: b750214@ (W.C.); clcheng1688@ (C.-L.C.) * Author to whom correspondence should be addressed; E-Mail: huamy@.tw; Tel.: +886-3-211-8800 ext. 5289; Fax: +886-3-211-8668. Received: 30 March 2011; in revised form: 25 May 2011 / Accepted: 30 May 2011 / Published: 31 May 2011 Abstract: A series of dopant-type polyaniline-polyacrylic acid composite (PAn-PAA) films with porous structures were prepared and developed for an enzyme-free hydrogen peroxide (H O ) sensor. The composite films were highly electroactive in a neutral environment as 2 2 compared to polyaniline (PAn). In addition, the carboxyl group of the PAA was found to rea