自燃煤矸石吸附磷的动力学和热力学-环境工程学报.PDFVIP

第 11卷　 第7 期 环 境 工 程 学 报 Vol. 11,No.7 2 0 1 7 年 7 月 Chinese Journal of Environmental Engineering July 2 0 1 7 自燃煤矸石吸附磷的动力学和热力学 丁伟,巴图其木格,张玲玲,白淑琴∗ 内蒙古大学生态与环境学院,呼和浩特 010021 摘　 要　 自燃煤矸石作为吸附剂对水溶液中的磷酸盐有较好的吸附去除作用。 通过改变时间、溶液初始浓度和温度等条 件,研究了自燃煤矸石对磷酸盐的吸附反应。 结果表明,在298 K 的条件下,自燃煤矸石对磷的最大饱和吸附量可达 7.07 -1 mg ·g ,吸附平衡时间约为 120 h,而且吸附数据符合 Langmuir 等温吸附模式。 动力学研究数据表示,其吸附过程符合伪 二级动力学模式和颗粒内扩散模式,证明了吸附过程中同时发生了化学吸附和物理吸附。 吸附热力学参数自由能变 ΔG为 -1 -1 -1 ( -10.52,-11.74,-14.89)kJ ·mol ,焓变 ΔH 为46.96 kJ ·mol 和活化能E 为63.71 kJ ·mol ,证明了吸附过程属于 自发的吸热反应,是属于物理吸附和化学吸附的共同作用。 关键词　 自燃煤矸石;磷酸盐;吸附机理 中图分类号　 X703　　 文献标识码　 A　　 文章编号　 1673-9108(2017)07-4059-08　　 DOI:10.12030/ j.cjee.201604165 Kinetic and thermodynamic study of phosphate adsorption by Spontaneous combustion coal gangue DING Wei,BATCHIMEG,ZHANG Lingling,BAI Shuqin∗ School of Ecology and Environment,Inner Mongolia University,Hohhot 010021,China Abstract　 Spontaneous combustion coal gangue has good adsorption ability for removing phosphate in aqueous solution.The adsorption of phosphate by spontaneous combustion coal gangue was therefore studied.The influ- ences of adsorption time,initial concentration of phosphate solutions,and temperature on the adsorption of phos- phate were observed.The results indicate that the maximum adsorption of phosphate was 7. -1 07 mg ·g , the phosphate adsorption equilibrium was attained after 120 h,and the adsorption process was well-fitted to a Lang- muir adsorption isotherm when the temperature was298 K.The study of adsorption kinetics shows that it was also well-fitted to the patterns of pseudo second-order and particle diffusion models, indicating the coexistence of chemical adsorption and phy