some anilides of 2-alkylthio- and 2-chloro-6-alkylthio-4-pyridinecarboxylic acids synthesis and photosynthesis-inhibiting activity一些苯胺2-alkylthio和2-chloro-6-alkylthio-4-pyridinecarboxylic酸的合成和photosynthesis-inhibiting活动.pdfVIP

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some anilides of 2-alkylthio- and 2-chloro-6-alkylthio-4-pyridinecarboxylic acids synthesis and photosynthesis-inhibiting activity一些苯胺2-alkylthio和2-chloro-6-alkylthio-4-pyridinecarboxylic酸的合成和photosynthesis-inhibiting活动.pdf

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some anilides of 2-alkylthio- and 2-chloro-6-alkylthio-4-pyridinecarboxylic acids synthesis and photosynthesis-inhibiting activity一些苯胺2-alkylthio和2-chloro-6-alkylthio-4-pyridinecarboxylic酸的合成和photosynthesis-inhibiting活动

Molecules 2001, 6, 603-613 molecules ISSN 1420-3049 Some Anilides of 2-Alkylthio- and 2-Chloro-6-Alkylthio-4- Pyridinecarboxylic Acids: Synthesis and Photosynthesis- Inhibiting Activity 1* 1 1 1 2 Miroslav Miletín , Martin Doležal , Veronika Opletalová , Jiří Hartl , Katarína Král’ová , and Miloš Macháček3 1 Department of Medicinal Chemistry and Drug Control, Charles University, Faculty of Pharmacy, 500 05 Hradec Králové, Czech Republic; 2 Institute of Chemistry, Faculty of Natural Sciences, Comenius University, Bratislava, Slovak Republic 3 Department of Inorganic and Organic Chemistry, Charles University, Faculty of Pharmacy, 500 05 Hradec Králové, Czech Republic * Author to whom correspondence should be addressed; e-mail miletin@faf.cuni.cz, tel. +420 49 5067387, fax +420 49 551 24 23. Received: 16 February 2001; in revised form 28 May 2001 / Accepted: 1 June 2001 / Published: 30 June 2001 __________________________________________________________________________________ Abstract: Many compounds containing a -CONH- group display photosynthesis inhibiting activity. Based on this structural feature, a group of anilides of 2-alkylthio- (1b-4f) or 2-chloro-6-alkylthio-4-pyridinecarboxylic acids (5a-6c) was synthesised. The prepared compounds were tested for their inhibition of the oxygen evolution rate (OER) in spinach chloroplasts. A quasi-parabolic dependence between photosynthesis-inhibiting activity and the lipophilicity of the comp