state selective electron capture in the collision of s3+ ions in atomic hydrogen and helium国家选择性电子俘获在s3 +离子的碰撞原子氢和氦.pdfVIP

Int. J. Mol. Sci. 2004, 5, 265-275 International Journal of Molecular Sciences ISSN 1422-0067 © 2004 by MDPI /ijms/ State Selective Electron Capture in the Collision of S3+ Ions in Atomic Hydrogen and Helium Marta Łabuda 1,2, Y. Suzanne Tergiman 1, Marie-Christine Bacchus-Montabonel 1,* and Jozef E. 2 Sienkiewicz 1 Laboratoire de Spectrométrie Ionique et Moléculaire, UMR 5579, CNRS et Université Lyon I, 43 Bd. du 11 Novembre 1918, 69622 Villeurbanne Cedex, France 2 Department of Theoretical Physics and Mathematical Methods, Gdańsk University of Technology, ul. Narutowicza 11/12, Pl-80-952 Gdańsk, Poland * Author to whom correspondence should be addressed; e-mail: bacchus@lasim.univ-lyon1.fr Received: 8 September 2004; in revised form: 9 November 2004 / Accepted: 9 November 2004 / Published: 30 November 2004 Abstract: A full theoretical treatment including an ab-initio molecular calculation of the potential energy curves and couplings followed by a semi-classical collision dynamics has been performed for the one-electron capture by S3+ ions in collision with atomic hydrogen. The present paper completes a previous letter [9] and displays the full results concerning this process in order to provide a detailed understanding of the mechanism. These calculations show evidence of the predominance of the S2+ 2 3