synthesis of a diamino substituted terphenyldivinyl chromophore合成的二氨基取代terphenyldivinyl发色团.pdfVIP

下载本文档

1
0
约2.02万字
约 7页
2017-09-12 发布于上海
举报
版权申诉

synthesis of a diamino substituted terphenyldivinyl chromophore合成的二氨基取代terphenyldivinyl发色团.pdf

1、本文档共7页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

synthesis of a diamino substituted terphenyldivinyl chromophore合成的二氨基取代terphenyldivinyl发色团

Molecules 2009, 14, 2111-2117; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore Zhen-Ting Du 1,*, Ru Liu 1, Jun-Ru Wang 1 and An-Pai Li 2,* 1 College of Sciences, Northwest AF University, Yangling, Shaanxi 712100, China; E-mails: liuru75@ (R.L.), wangjr07@163.com (J-R.W.) 2 Synthetics Technologica Pte Ltd, 3 Phillip Street, #18-00 Commerce Point, 048693, Singapore; E-mail: anpaili@ (A-P.L.) * Author to whom correspondence should be addressed; E-mail duzt@; Tel.: +86-29 Fax: +86-29 Received: 24 April 2009; in revised form: 1 June 2009 / Accepted: 3 June 2009 / Published: 10 June 2009 Abstract: (E,E)-1,4-bis(4-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W. Keywords: chromophore; energy transfer; synthesis; terphenyldivinyl Introduction As we all know, photosynthesis is the most important way on which all the lives in our planet depend directly or indirectly. Now, photosynthesis has been understood as a series sequence of energy and charge transfer in plants or microorganisms. Some photo-voltaic processes are designed based on mechanism