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tetrachloridocuprates(ii)—synthesis and electron paramagnetic resonance (epr) spectroscopytetrachloridocuprates(ii)合成和电子顺磁共振(epr)谱
Int. J. Mol. Sci. 2012, 13, 1612-1619; doi:10.3390/ijm
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/journal/ijms
Article
Tetrachloridocuprates(II)—Synthesis and Electron
Paramagnetic Resonance (EPR) Spectroscopy
Alette Winter, André Zabel and Peter Strauch *
Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam/Golm,
Germany; E-Mails: awinter@uni-potsdam.de (A.W.); azabel@uni-potsdam.de (A.Z.)
* Author to whom correspondence should be addressed; E-Mail: pstrauch@uni-potsdam.de;
Tel.: +49-331-977-5190; Fax: +49-331-977-5268.
Received: 4 January 2012; in revised form: 23 January 2012 / Accepted: 29 January 2012 /
Published: 2 February 2012
Abstract: Ionic liquids (ILs) on the basis of metal containing anions and/or cations are of
interest for a variety of technical applications e.g., synthesis of particles, magnetic or
thermochromic materials. We present the synthesis and the results of electron paramagnetic
resonance (EPR) spectroscopic analyses of a series of some new potential ionic liquids
based on tetrachloridocuprates(II), [CuCl4]2−, with different sterically demanding cations:
hexadecyltrimethylammonium 1, tetradecyltrimethylammonium 2, tetrabutylammonium 3
and benzyltriethylammonium 4. The cations in the new compounds were used to achieve a
reasonable separation of the paramagnetic Cu(II) ions for
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