不同形貌TaCx晶须的制备及生长机理.PDF

TaCx 15 T aCx Preparat ion and Growth Mechanism of Different M orphological T aCx Whiskers , , , ( , , 10008 ) CHEN Yong-jun, LI Jian-bao, WEI Qiang-min, ZHAI Hua-zhang ( State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua U niversity , Beijing 10008 , China) : ( TaC ) T a O -NaCl-C-Ni T a O -NaF- x 2 5 2 5 C-C H O ( ) , -- (VLS) T a O -KCl-C-Ni 12 22 11 2 5 VLS , LS , , , , : T aC ; ; x : T Q 17 : A : 1001- 381 (2002) 10-0015-0 : ( x ) Abstract T antalum carbide T aC w hiskers were successfully synthesized via different methods and different starting raw materials in the presence of Ni pow der used for the catalysis of synthesis. 2 5 - - - 2 5 - - - 12 22 11 ( ) In the Ta O NaCl C Ni and Ta O NaF C C H O sucrose systems the whiskers grew via a - - ( ) . 2 5 - vapor liquid solid VLS mechanism and exhibit a fairly straight fiber morphology In the Ta O - - , . KCl C Ni system some w hiskers grew via a VLS mechanism and others via a LS mechanism Some w hiskers grew w ith a zigzag shape tip and conical shaped morphology. All w hiskers w ere grow n under similar reaction conditions at temperatures w hich range from 1150 to 1350 in a nitrogen ambient atmosphere. The compos