石墨烯基环氧树脂复合热界面材料的制备及热性能-硅酸盐学报.PDFVIP

第45 卷第1 期 硅 酸 盐 学 报 Vol. 45 ，No. 1 2 0 1 7 年 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY January ，2017 DOI ：10.14062/j.issn.0454-5648.2017.01.18 石墨烯基环氧树脂复合热界面材料的制备及热性能 唐 波，许继星，黄维秋 (常州大学，江苏省油气储运技术重点实验室，常州 江苏 213016) 摘 要：采用氧化还原法制备的石墨烯作为改性材料，研究石墨烯的含量及其还原程度对环氧树脂热导率的影响，并进一步 测定复合热界面材料的热导率在高温下的稳定性。结果表明：石墨烯可以大幅提高环氧树脂的热导率，加入质量分数为15% 的石墨烯可以使环氧树脂的热导率提高2 300% 。石墨烯表面的剩余官能团对产物的热导率也有显著的影响，表面官能团可以 充当声子输运通道并减小界面间的 Kapitza 热阻，但是过多的表面官能团会减小石墨烯的本征热导率。经过优化还原时间， 复合热界面材料的热导率得到进一步的提高。另外，通过优化石墨烯的还原程度及尺寸，提高了复合材料产物热导率在高温 下的稳定性。 关键词：热界面材料；石墨烯；Kapitza 热阻；环氧树脂；表面官能团 中图分类号：TB332 文献标志码：A 文章编号：0454–5648(2017)01–0126–06 网络出版时间： 网络出版地址： Preparation and Thermal Performances of Graphene Modified Epoxy Resin TANG Bo, XU Jixing , HUANG Weiqiu (Jiangsu Provincial Key Laboratory of Oil Gas Storage and Transportation Technology, Changzhou University, Changzhou 213016, Jiangsu, China) Abstract: Reduced graphene oxide (RGO) nanosheets were adopted as a modifier to improve the thermal conductivity of epoxy resin (ER), and the influences of the content and reduction degree of the RGO nanosheets on the thermal properties of thermal interface materials (TIMS) were investigated. The results demonstrate that the thermal conductivity increases 2 300% after adding 15% RGO nanosheets into the ER. Moreover, the thermal conductivity of the resultant composite is closely related to the residual amount of surface functional groups of the RGO. The presence of surface functional groups can act as a bridge to improve the phonon transport between graphene basic plane and ER (which promotes the better match of phonon DOS between th