第7章 化学动力学基础（The seventh chapter is the basis of chemical kinetics）.doc

第7章 化学动力学基础（The seventh chapter is the basis of chemical kinetics） The seventh chapter is the basis of chemical kinetics [Topic 1] chemical reaction rate [teaching purposes] 1. master the expression of the speed of chemical reaction 2. grasp the influence of concentration (Law of mass action) on the rate of reaction [heavy and difficult] The rate equations are established and the rate equations are used for calculation [class arrangement]2 hours [teaching methods] explain [teaching process] [verse] the first chemical reaction rate I. average rate: the rate of chemical reaction is expressed by the concentration of any reactant in a unit time or the concentration of the resultant. The unit of concentration is mole / liter, and the time unit is expressed in seconds, minutes, or hours depending on the speed of the reaction. Therefore, the rate of reaction is mole / liter time. [blackboard writing] general chemical reaction: aA+bB=gC+dD [] if on the concentration of a substance to change different reaction speed, due to measurement between the reaction rate with chemical reaction, so the material will use the coefficient of molecular representation of the reaction rate divided by the corresponding type before, they have the same value. That is: Or: The calculated reaction speed is the average rate of reaction in that period of time. [two] instantaneous speed: the rate of reaction at an instant is called instantaneous reaction speed. [explanation] if the reaction to ammonia can be expressed as: Instantaneous reaction rate can be obtained by graphical method: known in the CO+NO2CO2+NO reaction, the vertical axis represents the CO concentration of reactants, the abscissa represents time mapping to figure 6-1. To obtain the reaction rate at a given time of T, such as t = 10s, Can draw a straight line parallel to the longitudinal coordinates in the horizontal coordinate 10s, and curves intersect at point a, a by a dotted tangent, the tangent slope is the instantaneous reactio