溶液中离子浓度大小的比较及其规律与应用(Comparison of ionic concentration in solution and its law and Application).docVIP
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溶液中离子浓度大小的比较及其规律与应用(Comparison of ionic concentration in solution and its law and Application)
溶液中离子浓度大小的比较及其规律与应用(Comparison of ionic concentration in solution and its law and Application)
Comparison of ionic concentration in solution and its law and Application
Ion concentration in the salt solution in the hour of judgment can be hydrolyzed, we must first clear the salt is strongly ionized, hydrolysis is weak, then clear hydrolysis of polybasic acid salt is carried out step by step, and the first step is the main, finally, dont forget to water ionization.
Ionization and hydrolysis of the two processes to produce ions or to change the concentration of ions, so the comparison of the concentration of ions generally from the two aspects of the test. A common type of inequality between the test and the equality relationship between the true or false true or false two.
Inequality relation
(1) polybasic weak acid solution
The existence of H2S solution with ion concentration in 1.0.1mol/L sequence from large to small is __________.
Analysis: H2S H+ + HS in H2S solution, HS - H+ + S2, because the first step to polybasic ionization, the second step is the first step of ionization is much weaker, but the two step ionization H+.
Answer: C (H+), C (HS), C (S2), C (OH -).
I judge the general law of ion concentration in the solution is the size of the polybasic acid: (dominant ion) (an ion (two) (ion) another ion water ionization out)
(2) normal salt solution, a weak dollar.
The existence of CH3COONa solution with ion concentration in 2.0.1mol/L sequence from large to small is ______.
Analysis: in CH3COONa solution CH3COONa = Na+ + CH3COO, CH3COOH + H2O CH3COO+ Oh -, so that the C (CH3COO) decreased and the solution is alkaline, C (Na+), C (CH3COO), C (OH -), C (H+). Because the hydrolysis degree of salt is generally smaller, there is C (CH3COO -) C (OH -).
Answer: C (Na+), C (CH3COO), C (OH -), C (H+).
I judge the general law of salt ion concentration in the solution of weak dollar size is: (not hydrolyzed ion) (hydrolysis ions) (dominant ion) (another ion of ioni
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