应用低场核磁共振技术分析烟丝样品含水率的方法-中国烟草学报.PDFVIP

6 中国烟草学报　2014 年 10 月 第 20 卷 第 5 期 应用低场核磁共振技术分析烟丝样品含水率的方法 1,2 1 2 3 1* 梁国海 ， ， ， ， 刘百战 朱仲良 孔继烈 瞿永生 1 上海烟草集团有限责任公司技术中心，上海 200082; 2 同济大学化学系，上海 200092 ； 3 复旦大学化学系，上海 200433 摘　要: 建立了基于核磁共振硬脉冲自由感应衰减信号（FID ）的含水率测定方法。以烟丝样品为模型，在预先建立的工作函数 基础上，可对多个样品水分进行快速测定。以核磁共振法与烘箱法的结果进行比较，结果显示核磁共振法具有理想的重复性、精 密度和稳定性，5 次平行测定结果的标准偏差小于 0.5%，4 天内测得的样品含水率极差为 0.45% 。 关键词：低场; 核磁共振；烟丝；含水率；FID 信号 doi ：10.3969/j.issn.1004-5708.2014.05.002 中图分类号：TS411　　　文献标志码：A　　　文章编号：1004-5708 （2014 ）05-0006-06 The application of low-field nuclear magnetic resonance ( NMR ) to moisture determination in cut-tobacco 1,2 1 2 3 1 LIANG Guohai , LIU Baizhan , ZHU Zhongliang , KONG Jilie and QU Yongsheng 1 Technical Center, Shanghai Tobacco Group Co., Ltd., Shanghai 200082, China; 2 Department of Chemistry, Tongji University, Shanghai 200092, China; 3 Department of Chemistry, Fudan University, Shanghai 200433, China Abstract: A novel method for detecting moisture content in cut tobacco based on free induction decay (FID) signals by low-field nuclear magnetic resonance(NMR) was established. The method was validated by measuring moisture content in cut-tobacco samples. Comparison between NMR method and Oven-drying method showed that the former had good repeatability, accuracy and stability with RSDs of 5 parallel tests lower than 0.5% and sample range of moisture within 4 days being 0.45%. Keywords: low-field; nuclear magnetic resonance(NMR); cut-tobacco; m