锂离子电池硅纳米线负极材料研究（Study on silicon nanowire negative electrode materials for lithium ion batteries）.docVIP

锂离子电池硅纳米线负极材料研究（Study on silicon nanowire negative electrode materials for lithium ion batteries） This article is contributed by tabwol007 Pdf documents may experience poor browsing on the WAP side. It is recommended that you first select TXT, or download the source file to the local view. Volume 1, fifteenth, 2009th, February Electrochemistry ELECTROCHEM ISTRY Vol 15, No. 1., Feb. 2009 Study on silicon nanowire negative electrode materials for lithium ion batteries Fu Yanpeng, Chen Huixin, Yang Yong Three (State Key Laboratory of physical chemistry of solid surfaces, Department of chemistry, School of chemistry and chemical engineering, Xiamen University, Fujian, Xiamen 361005, China) Two kinds of silicon nanowire electrodes were prepared by coating method and direct growth method. XRD, SEM and charge discharge curves were characterized, observed and summarized: The determination of structure, morphology and electrochemical properties of lithium intercalation processes. Compared with the coating method, direct film preparation of silicon nanowire electrode has high specific capacity and good cycle life and better rate performance; direct film preparation of silicon nanowire electrode, the intercalation process of silicon by the crystal gradually transformed into amorphous, and the diameter of the nanowires increases, but the linear structure remains intact, thus preventing the electrode pulverization and peeling. Keywords:; nanowires; cathode materials; lithium ion batteries; electrochemical properties; coating method; direct growth of silicon film: TM911 documentcode: A silicon anode material is currently found with the highest theoretical capacity of lithium storage (4200 mAh / g), the specific capacity is much higher than that of graphite materials but, its actual lithium electrode and silicon electrode size, composition and charge discharge rate and other factors are closely related. At the same time, the silicon anode materials in high intercalation / deinterc