南阳独山玉的矿物学研究-维普网.PDFVIP

维普资讯 第 1期 浊伏棱 (Povlen)型羟基纤蛇纹 的谱学研究 A Spectroscopic Study ofPovlen Type Hydroxyl-Chrysotile Zhu Hehao (1nstitato ofGeoche~ try，Ac 1euj4 Sinica) JiangShaoying cIn l【te ofGo~ogy ·~finistry ~ dlctlug Materials} ShaoHanru，W u weifang ([nstitutaofHigh Energy physics，Academia sinica) Key words：Serpentine；absorption spectrum ；infrared spectrum ； M Ossbauer spectrum ；EPR spectrum ； NMR specrtum A [~tract PovIen type hydroxyl—chrysotile is a new variety of Povlen type chrysotile，whose absorption，infrared，M6ssbauer，EPR and NMR spectra are reported in thispaper． Experimentation shows that *he absorption specrta are caused by Crysat l-fieldrtansit／onsof1；e。 and Fe ions and charge-rtansfer transition ofFe -+Fe”，the infrarde specrtaby srtetching vibrat／onsofOH and 一0， rotation of OH and bending vibrations of Mg-O and Si一0，the M6ssbauer spectrabyFe~c；… lZeL；．，andreTo7…，hteEPR specrta byMn ．．Fe嚣。 and Fe ，and the NMR spectrabypjpewaterinfibreandOHonMg—octaherda and Si一0 tertahedra．It is also demonsrtated that，when heated to 825℃ ， ht esrtUc~trewasdestroyed and forsterite phase formde ． In additionJthispaper interpretstheColorofPovlentypehydroxyl—ohryso— tile and describes srtuctural environm entsof theabove tranrdtionnlm e％aliong and 0H in thism ineraJ． 南阳独山玉的矿物学研究 张建洪 李朝晖 汪雪芳 (中国地 质大学 ，北京) 主题词 ；南 阳独山玉，钙 匠石，黝帘石 ，铬绿帘石 ，含铬珍珠云母 提 墨：南阳独山玉呈脉状产于河南省南阳市独山透闪石化辉长岩岩体内。笔者选择 了各种代 维普资讯 岩 石 矿 物 学 杂 志 表性样品c白玉、绿玉、白绿玉、棕黑色玉)，对其进行了光薄片显徽镜丽察、捧针、