烃组分组分含量限值-天然气与石油.DOCVIP

Selexol脱碳工艺的参数优化及适应性研究 张哲1 皮艳慧2 （1.中石油规划总院2.西南石油大学国家重点实验室 成都 610500） 摘 要对于高含碳、微含H2S的特殊天然气气藏，Selexol脱碳工艺因其溶剂绿色环保、腐蚀性小而受到了越来越多的关注与研究。利用HYSYS 2006软件优化Selexol工艺的吸收塔控制参数以及闪蒸再生条件，进一步体现Selexol工艺的适应性。结果表明：吸收塔操作条件为原料气入塔温度-5~5℃，贫液注入量750m3/h左右，注入温度越低越佳，实际运行中不得低于-18℃。闪蒸再生时，优化的三级压力分别为2400kPa、500kPa和50kPa。Selexol工艺适用于CO2含量在60%以下，C4+重烃小于1%（V）的贫天然气脱碳处理。 关键词高含碳天然气Selexol，脱碳优化适应性The Process Parameter Optimization and Adaptive Research of Selexol decarburization Zhang Zhe1,Pi Yanhui2,Chen Siding2 (1.PetroChina Planning Engineering Institute, Beijing, 100083; State Key Laboratory of Southwest Petroleum University, Chengdu, 610500) Abstract: In view of special gas reservoirs of high carbon and micro containing of H2S, Selexol decarburization process has been subjected to more and more attention and research for its green solvent and less corrosive. The absorber control parameters of Selexol process as well as the flash regeneration conditions were optimized by the HYSYS 2006 software, thus further reflected the adaptability of Selexol process. The results show that the absorption tower operating conditions is that temperature of feed gas into the tower is -5 to 5 °C , poor liquid injection rate is about 750m3 / h , the lower of injection temperature the better, injection temperature in the actual operation shall not be lower than -18°C.The respectively optimized three pressure are 2400kPa, 500kPa and 50kPa. Selexol process is adequate for the depleted gas decarburization treatment whose content of CO2 is less than 60% and C4 + heavy hydrocarbons is less than 1% (V). Keywords: natural gas of high content of carbon, Selexol, decarburization, optimization, applicability 0.引言 Selexol脱碳工艺因其吸碳率高、处理量大、对环境无害、能耗低以及可基本实现100%CO2的回收利用等优点被认为是天然气净化工业中最有前途的物理溶剂脱碳法。国外很早就开始研究采用Selexol工艺用于天然气脱碳，并且已经有多套成熟的工业应用装置。至今为止，国内有报道的Selexol装置全部应用于合成气的净化处理，在天然气脱碳处理方面的应用研究处于起步阶段，尚未有成功应用的工业化装置。 因此，研究Selexol工艺用于天然气脱碳的参数优化与适应性，对降低脱碳处理装置的能耗和成本，实现国内高含碳气藏的高效、节能开发，保证生产及运行的稳定性等有重要的工程实际指导意义。 1.Selexol工艺特性 Sele