物理化学的（Physicochemical）.docVIP

物理化学的（Physicochemical） Classical exercises of Physical Chemistry Fill in the blanks 1., sulfuric acid and water can form three kinds of hydrate: H2SO4, H2O, H2SO4, 2H2O, H2SO4, 4H2O. Under normal pressure, a certain amount of H2SO4 is dissolved in water, and when the three-phase equilibrium is reached, the number of water molecules in the hydrated salt of sulfate hydrate that can coexist with ice and H2SO4 water is. The reduction of electrode potential and H+ were 2.Na+ - 2.71V and - 0.83V, but with Hg as cathode in NaCl solution, the cathode product is Na - Hg, but not H2, this phenomenon is explained. 3. arsenic sulfide solution was prepared by the addition of excess hydrogen sulfide in dilute arsenic acid solution. The micelle structure is. Note the close layer, diffusion layer, gum core, colloidal particle and micelle. 4. in between two containers with 0.001mAgNO3 solution is a AgCl multi hole plug, and two electrodes are placed at both ends of the multi hole plug to connect the DC power supply, and the solution will flow in the extreme direction. 5. reaction A, B (I); A, D (II). The activation energy of the known reaction (I) is greater than the activation energy of reaction (II), and the ratio of B to D is obtained by adding proper catalyst. 6. isothermal isobaric (298K and P?) under the condition of a chemical reaction in the non volume work condition, release 40 kJ? Mol-1, if to complete the reaction by reversible battery, absorbing 4 kJ? Mol-1, the entropy change of chemical reaction for. 7. if the C dilute solution surface tension and solute concentration of gamma gamma 0, gamma = A + B ln C (gamma 0 for pure solvent surface tension, A and B, it is a constant) solute in the relationship between adsorption quantity and gamma concentration of C solution on the surface of the. 8.298.2K, 101.325kPa, H2 (g) + O2 (g) H2O (L) (one of the? RGm? RFm) / J mol-1?. Two. Questions and answers 1., why is heat and power conversion irreversible? The 2. is a chemical react