分析化学(高教版)习题详解（Detailed explanation of exercises in Analytical Chemistry (Higher Education Edition)）.docVIP

分析化学(高教版)习题详解（Detailed explanation of exercises in Analytical Chemistry (Higher Education Edition)） The third chapter is titration analysis Thinking question 1. what is titration analysis? What are the main methods of analysis? Answer: a solution using the buret reagent that accurately known concentration of standard solution is dripped into the analyte solution, until the object component is exactly the reaction, adding standard solution and the amount of substance of the component to be measured the amount of substance with stoichiometry reaction, then according to the concentration of standard the solution and the consumption volume, calculate the analyte content, this kind of method is called titration analysis. According to the chemical reactions used, titration analysis can be divided into acid-base titration, precipitation titration, complexometric titration and redox titration. 2. what conditions must be met for a chemical reaction that can be used for titration analysis? Answer: there are many chemical reactions, but the chemical reactions that are suitable for titration must meet the following conditions: (1) the reaction was completed quantitatively, i.e., the reaction was performed according to a certain reaction formula without any side effects, and it was complete (99.9%), which was the basis of quantitative calculation. (2) the reaction rate is fast. For slower rate reactions, appropriate measures should be taken to increase the rate of reaction. (3) the end-point of titration can be determined by a simpler method. Any reaction that meets the above requirements can be used in direct titration, i.e., direct titration of the substance to be measured with standard solutions. 3. what is a stoichiometric point? What is the destination? Answer: the drop of standard solution and the component to be measured exactly react, this is called the stoichiometric point. An indicator is added to the solution to be tested, and the titration is stopped when the indicat