低煤阶煤的煤岩成分液化性能及试验研究-煤炭学报.PDF

摇 第35卷第6期 煤摇 摇 炭摇 摇 学摇 摇 报 Vol.35摇 No.6摇 摇 2010年 6月 JOURNAL OF CHINA COAL SOCIETY June摇 2010摇 摇 摇 文章编号:0253-9993(2010)06-0992-06 低煤阶煤的煤岩成分液化性能及实验研究 晋香兰,降文萍,李小彦,张摇 泓,田新娟 (煤炭科学研究总院西安研究院,陕西摇 西安摇 710054) 摘摇 要:以西北侏罗纪煤中的镜煤和丝炭为研究对象,液化实验结果表明:同一变质程度的镜煤的 液化转化率(90郾67%)、油产率(58郾88%)均高于丝炭;而不同变质程度的镜煤和丝炭,因其结构和 性质的差异,随变质程度的增高,液化性能整体呈降低趋势。 镜质组和惰质组分别作为镜煤和丝炭 的主要物源,形成于截然不同的泥炭沼泽环境,致使结构和性质差异大。 显微组分特征、红外光谱 和分子结构模型分析表明:镜煤中活性组分含量高,H含量和脂肪氢含量高,大分子结构模型中21 个单芳环,具有芳香性的吡咯环2 个;丝炭中活性组分含量低于镜煤,含氧官能团多,碳含量和芳香 氢含量高,大分子结构模型中14 个单芳环、6 个双芳环、1个三芳环,具有芳香性的吡咯环2 个。 关键词:低煤阶煤;镜煤;丝炭;煤直接液化;红外光谱;分子结构模型 中图分类号:TQ529摇 摇 摇 文献标志码:A Liquefaction properties and experiment on lithotype of low rank coal JIN Xiang鄄lan,JIANG Wen鄄ping,LI Xiao鄄yan,ZHANG Hong,TIAN Xin鄄juan (Xi爷anResearch Institute,China CoalResearch Institute,Xi爷an摇 710054,China) Abstract:Vitrain and fusainofJurassiccoalinNorthwest Chinawasstudiedforliquefaction,theresultshowsthatcon鄄 version yieldandoilyieldofvitrainarehigherthansamemetamorphosefusainandtheliquefactionyieldofvitrainand fusain of differentmetamorphosedecreasewiththeincreasingof metamorphosebecauseof different structureandprop鄄 erty.Vitrinite and inertinite were formed distinct peat swamp environment as main origin of vitrain and fusain,which was essential reason for liquefaction properties.Coal maceral,infrared鄄ray spectra and molecular structure mode indi鄄 cate that vitrian has higher active components,hydrogen and aliphatic hydrogen,with twenty鄄one single aromatic rings and two aromaticpyrroleringsin molecular structure mode.Whereasthe active componentsof fusain arelessthanvit鄄 rain,with more oxygen鄄containing functional group,higher carbon,aromatic hydrogen,fourteen single aromatic rings, six double