郑州北郊水源地沉积物中砷的含量及形态分布研究.pdfVIP

网络出版时间：2013-10-15 15:05 网络出版地址：/kcms/detail/37.1440.N1505.011.html 郑州北郊水源地沉积物中砷的含量及形态分布研究 * 陈 英，孙英杰 ，王芳芳，王亚楠，吕 谋，张大磊 （青岛理工大学环境与市政工程学院，青岛 266033 ） 摘 要：以郑州市北郊水源地为研究区，在水砷超标与不超标地下水井附近钻孔取样，选取10 个地层沉 积物，分析不同粒径沉积物总砷的含量；利用Tessier 修正法提取沉积物中不同形态的砷，分析不同形态 砷的分布以及不同形态砷与沉积物理化指标间的相关性。研究表明，不同粒径沉积物总砷的含量多少依 次为：黏土粉黏粉土细砂 中砂；不同形态砷的分布顺序为：残渣态弱有机态/强有机态铁锰氧化 态水溶态碳酸盐结合态/离子交换态，残渣态砷是该研究区沉积物砷的主要形态；沉积物水溶态砷与 pH 呈显著正相关；铁锰氧化态砷与pH 呈显著负相关，与有机质、铁、锰均呈正相关；强、弱有机态砷 与pH 呈显著负相关，与有机质呈正相关；离子交换态砷、碳酸盐结合态砷受沉积物理化性质的影响不 大；残渣态砷与pH 、有机质、铁、锰关系密切。 关键词：沉积物；砷；含量；形态分析；Tessier 修正法 中图分类号：X53 文献标志码：A 文章编号：1673-4602 （2013 ）05-0000-00 Research on arsenic content and its speciation distribution in sediments of north suburb water source field in Zhengzhou * CHEN Ying, SUN Ying-jie , WANG Fang-fang, WANG Ya-nan, LÜ Mou，ZHANG Da-lei (School of Environmental and Municipal Engineering, Qingdao Technological University, Qingdao 266033, China) Abstract ：The northern suburb water source field in Zhengzhou is taken as the studied area. The drilling samples around two groundwater wells are different according to the concentration of arsenic. Ten samples are chosen for analyzing the distribution of total arsenic contents in sediments with different particle size. Tessier correction extraction method is used to extract the arsenic of different speciation. The speciation distribution of arsenic and its correlation with the physical and chemical indexes of sediment are analyzed. The results show that the order of arsenic content