电解质材料和绝缘.pptVIP

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电解质材料和绝缘

From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (? McGraw-Hill, 2005) 7.3.1离子极化 又称为原子极化,是在正负离子组成的物质中异极性离子沿电场向相反方向位移形成电偶极矩pa。pa与有效电场成正比,pa=αaE,αa称为离子极化率。电子极化和离子极化都都同温度无关。 7.3 其他极化机制 Fig 7.9 From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (? McGraw-Hill, 2005) (a) A NaCl chain in the NaCl crystal without an applied field. Average or net dipole moment per ion is zero. (b) In the presence of an applied field the ions become slightly displaced which leads to a net average dipole moment per ion. From Principles of Electronic Materials and

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