化学修饰电极在重金属中的研究与应用.docVIP

化学修饰电极在重金属检测中的应用及新的进展 摘要：通过羧基化水溶性碳纳米管，建立了测定水样中痕量镉。利用羟基化水溶性碳纳米管作为增敏剂，经吸附富集、用方波溶出伏安法测定痕量镉。讨论了吸附溶出的机理，对富集时间、对镉的浓度、富集电位及部分离子干扰等进行试验，并对含镉水样进行测定。进而深入了解化学修饰电极在重金属检测中的应用. 关键词：羧基化水溶性碳纳米管、方波溶出伏安法、镉、化学修饰电极 Abstract :Transit the water-solublecarboxylic carbon nanotube set up a way to meter the trace cadmium. Water-soluble carboxylic carbon nanotube used as a sensitizing agent for the square wave anodic stripping volltammetric measurement of trace cadmium.Possible adsorption and stripping mechanism were discussed.The electrochemical response was charactreized with respec to accumulation time,cadmium conce