二试验原理及工艺流程-有色金属（冶炼部分）.DOCVIP

低浓度铜阳极泥加压浸出液中银硒碲的分离 钟清慎1，2, 贺秀珍1，刘玉强1，2，马玉天1 （1.金川集团股份有限公司 贵金属研究中心,甘肃金昌，737100 2.西安建筑科技大学 冶金工程学院，陕西西安，710055） 摘要：对于低浓度铜阳极泥加压浸出液中银硒碲的分离，分别进行了铜粉置换的热力学分析、单因素影响置换试验、以及银硒碲的分步置换试验和铜粉分步置换Ag、Se，结晶母液铜粉置换沉淀Te的试验研究，结果表明：控制置换反应温度分别为≤45℃（低温）、≤75℃（中温）、≥95℃（高温）时，可以分别得到以银为主的银渣、以硒为主的硒渣和含银硒很低的碲渣，当铜阳极泥加压浸出液的碲浓度很低时，先采用铜粉分步置换Ag、Se，再结晶脱铜，脱铜母液用铜粉置换，碲置换率99%以上，碲置换渣碲质量分数高达36~43%，便于后续碲的提取与精炼。 关键词：低浓度铜阳极泥加压浸出液；铜粉置换；碲；硒；银；置换率 中图分类号：TF843.5;TQ125.3 文献标识码：A 文章编号： Separation of Silver, Selenium and Tellurium in Low Concentrations of Copper Anode Slime Pressure Leaching Solution ZhONG Qing-Shen1,2,HE Xiu-Zhen2,LIU Yu-Qiang1,2,MA Yu-Tian1 （1.Jin Chuan Precious Metalls Research Centre, Jin Chuan Group.Ltd,Jin Chang Gansu Province 737100,China,2.School of Metallurgical Engineering,Xi,an University of Architecture and Technology, Xi,an Shanxi Province 710055,） Abstract: for low concentration from copper anode slime pressure leaching liquid separation of silver, selenium and tellurium, respectively for the copper powder replacement of thermodynamics analysis, single factor affecting the displacement test, as well as the silver selenium tellurium step-by-step substitution test and copper powder replacement Ag, Se step by step, the crystallization mother liquor of copper powder cementation Te experimental study, the results show that the control displacement reaction temperature respectively for 45 ℃ or less (low temperature), 75 ℃ or less (temperature), and 95 ℃ or higher (high temperature), can be given priority to with silver silver, respectively is given priority to with selenium selenium residue and low silver selenium tellurium slag, when copper anode mud pressure leaching liquid of tellurium concentration is low, the first adopts copper powder, replacement Ag, Se, recrystallization of copper, copper removal mother liquor with copper powder replacement, tellurium replacement rate above 99%, tellurium slag replacement tellurium quality score as high as 36 ~ 43%, facilitate subsequent telluriu