K6SiW11O39SnⅡ多金属氧酸盐光催化降解染料废水研究.docVIP

摘 要 本文研究了多金属氧酸盐催化剂K6SiW11O39SnⅡ对甲基红，酸性大红，墨水蓝三种模拟染料废水的光催化性能。研究了染料溶液初始浓度、催化剂投加量、光照时间及溶液初始pH值等催化条件对催化剂光催化上述染料废水的催化效果的影响。 结果表明，多金属氧酸盐催化剂K6SiW11O39SnⅡ对甲基红，酸性大红，墨水蓝三种模拟染料废水的光催化反应效果不同。甲基红，酸性大红，墨水蓝模拟废水溶液的初始浓度、催化剂浓度、光解时间及溶液初始pH值等对其光解效果均有影响。对于pH为2.00，催化剂浓度为0.5g/L，初始浓度为10mg/L的20mL甲基红溶液，在阳光下光解1h，K6SiW11O39SnⅡ光催化甲基红溶液的脱色率为97.0% ；对于pH为2.00，催化剂浓度为1.25g/L，溶液初始浓度为3mg/L的20mL酸性大红溶液，在阳光下光解4h，K6SiW11O39SnⅡ光催化酸性大红溶液的脱色率为71.4% ；对于pH为2.00，催化剂浓度为1g/L，初始浓度为3mg/L的20mL墨水蓝溶液，在阳光下光解5h，K6SiW11O39SnⅡ降解墨水蓝溶液的脱色率为31.5% 。 关键词：K6SiW11O39SnⅡ 光催化 甲基红 酸性大红 墨水蓝 ABSTRACT The photocatalytic degradation characteristic of the polyoxometalate K6SiW11O39SnⅡ for simulation dye wastewater,which were methyl red, acid big red, blue ink solution,was studied. It showed that the decolorization efficiency of the reaction solution was affected by the catalyst quantity, the initial concentration of the dye solution,photodissociation time and the initial pH of the dye solution. The result shows that the polyoxometalate K6SiW11O39SnⅡ had effect on the photocatalytic degradation to methyl red, acid big red, ink blue aqueous solution.The initial concentration of methyl red ,acid big red, ink blue aqueous solution,catalyst quantity, photodissociation time and the initial pH of the dye solution all had effects on the decolorization rate of the solution. When the initial concentration of methyl red solution(20ml) was 10mg/L, pH was 2.00, the concentration of the catalyst was 0.5g/L, the methyl red solution was irradiated 1h under the sun, the decolorization rate of which was 97%. When the initial concentration of acid big red solution(20ml) was 3mg/L, pH was 2.00, the concentration of the catalyst was 1.25g/L, the acid big red solution was irradiated 4h under the sun, the decolorization rate of which was 71.4%. When the initial concentration of ink blue solution(20ml) was 3mg/L, pH was 2.00, the concentration of the catalyst was 1g/L, the ink blue solution was irradiated 5h under the sun, the decolorization rate of which was