中期总结低温等离子体催化净化有机废气机理研究.PPT

Effect of Oxygen Content on Toluene Decomposition in Wire-Plate Dielectric Barrier Discharge Reactor Guo Yufang Ph.D candidate South China University of Technology Introduction 1. Emission of various volatile organic compounds (VOCs) pollutes the air seriously. Dielectric barrier discharges (DBDs) processing has been considered as one of the most hopeful methods to remove VOCs. 2.In this study, an optimal oxygen content was  tested for the removal of toluene from gas  streams.Operational parameters: applied voltage gas flow rate  gas concentration with/without catalyst Experimental apparatus A Dielectric barrier discharge（DBD) reactor :wire-plate Figure 1. Simplified structure of the wire-plate DBD reactor Experimental setup  Results 1.The effect of oxygen concentration in the background gas 2. The Effect of Gas Flow Rates 3. The Effect of Initial Concentration of Toluene in Background Gas Figure 8. Dependences of ozone concentration on gas concentration ([O2]=5%, Q=500ml/min) 4. The Effect of Catalyst 5. byproducts CH4, C7H16 and C7H12 (no oxygen) benzene ,C4H4O3 ([O2]=5%) Discussion Oxygen plays a very important role in the reaction. e + O2 ＝ O + O(1D) (1) O+ O2 = O3 (2) H·+ O = OH· (3) A higher O2 content leads to the generation of more highly reactive O radicals , resulting in a higher removal efficiency. However, O2 has an adverse effect on toluene removal due to its electronegativity. So when the oxygen content is 10%, the removal efficiency is highest. Ozone as the main long-living radical is transported to the catalyst and can take part in heterogeneous oxidation reactions on its surface. This paper indicated a wire-plate diele