GPC常用溶加肓及方法.pptVIP

常用溶剂、方法以及多检测器比较 北京绿绵巨贸科贸有限公司 多检测器的比较 溶剂特性 各种样品所对应的溶剂条件 Polyisobutylene Polybutylene Chlorinated Rubber Polybutadiene Polyisoprene Polydimethylsiloxane Chlorinated Polyethylene Polyethylene – Ethylacrylate Polyethylene – Vinylacetone Polyethylene – Methacrylic acid Polyphenyleneoxide Poly-4-methylpentene(1) Polyethylene Ultra-high Molecular Weight Polyethylene Polypropylene Polyetheretherketone Polyetherketone Polycarbonate Polyglycolic acid Acrylonitrile – Methylmethacrylate Cellulose Acetate Cellulose Acetate – Butyrate Cellulose Acetate – Proprionate Cellulose Nitrate Cellulose Proprionate Cellulose Triacetate Diallyl Phthalate Ethyl Cellulose Epoxy Polyester Alkyd Polybutene(1) Polybutadiene – Styrene Phenol – Formaldehyde Phenol – Furfural Polymethylmethacrylate Polypropyleneglycol Polystyrene Polysulfone Polyvinylacetate Polyvinylbutyral Polyvinylchloride Polyvinylchloride – Acetate Polyvinyldienechloride Polyvinylformal Polystyrene Acrylonitrile Polystyrene – Alphamethylstyrene Polyester Thermoset Phenolics Rosin Acids Polyglycolic Acid 各种样品所对应的溶剂条件 Melamine – Formaldehyde Nylon (All types) Polybutylene – Terphthalate(PBT) Polyethylene – Terphthalate(PET) Poly Acrylonitrile(聚丙烯睛) ABS (Acrylonitrile – Butadiene – Styrene) ASA (Acrylic – Styrene – Acrylonitrile） ABA (Acrylonitrile – Butdiene – Acrylate) Carboxymethyl Cellulose ABS/Polycarbonate Polybutadiene – Acrylonitrile Polyurethane Polyacetal Polyoxymethylene Polyimide Polyamide – imide Polyetherimide Polyethersulfone Polyvinyldienefluoride Polyfuran – Formaldehyde * 绿绵巨贸 * 绿绵巨贸 能 能 准确结果 三检测器联用的GPC 能，当有两个测量角以上 能，但要符合一些假设 绝对测出，无需色谱柱校正 配了多角激光检测器的GPC 能，但是间接得到 能，直接从特性黏数测出 测出特性黏数，得到K/a值的普适校正 配了黏度检测器的GPC 不能 不能 需从文献上得到准确的K/a值，对相对分子量进行的色谱柱普适校正得到绝对分子量 使用普适校正的传统GPC 不能 不能 相对于标样的色谱柱校正，得到相对分子量 传统GPC 回转半径 支化 分子量 配置方法 58 1.02 12.2 Hexafluroisopropanol 六氟乙丙醇 153 0.9 12.1 Dimethyl formamide 二甲基甲酰胺 189 1.1 12 Dimethyl sulphoxide 二甲基亚砜 202 1.65 11.3 n-Methyl pyrrolidone 氮甲基吡咯烷酮 166 0.77 10.8 Dimethyl acetami