生物表面活性剂鼠李糖脂及其复配体系界面行为和性质的介观模拟.pdfVIP

2011 年第69 卷 化 学 学 报 Vol. 69, 2011 第20 期, 2420～2426 ACTA CHIMICA SINICA No. 20, 2420～2426 ·研究论文· 生物表面活性剂鼠李糖脂及其复配体系界面行为和性质的介观模拟 朱鹏飞a 李 英*,a 李全伟a 宋新旺b 曹绪龙b 李振泉b (a 山东大学化学与化工学院 胶体与界面教育部重点实验室 济南 250100) (b 中石化胜利油田地质科学研究院 东营 257015) 摘要 采用介观模拟耗散颗粒动力学(DPD)方法研究不同结构的鼠李糖脂在油/水界面行为差异和结构对活性的影响, 并探讨了其与不同类型表面活性剂如十二烷基硫酸钠(SDS)、十二烷基苯磺酸钠(SDBS)、脂肪醇聚氧乙烯醚(AEO3)复 配时体系的界面性质, 给出不同结构的鼠李糖脂的行为特点及与常用合成表面活性剂在油/水界面的相互作用规律, 以 指导实际应用. 关键词 生物表面活性剂; 鼠李糖脂; 复配增效; 耗散颗粒动力学模拟; 界面密度 Mesoscopic Simulation of the Interfacial Behavior of Biosurfactant Rhamnolipids and the Synergistic Systems Zhu, Pengfeia Li, Ying*,a Li, Quanweia Song, Xinwangb Cao, Xulongb Li, Zhenquanb a ( Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100) (b Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015) Abstract The interfacial behavior of rhamnolipids (RL) at the oil/water interface was studied using dissi- pative particle dynamics (DPD) method. The characteristic of the monorhamnose and dirhamnose rham- nolipids (R1 and R2) and their mixtures with conventional surfactants, such as sodium dodecyl sulfate (SDS), sodium dodecyl benzene sulfonate (SDBS) and fatty alcohol polyoxyethylene ether (AEO3) was studied. The interfacial behavior of R1 and R2 was studied and the effect of synergistic on the interfacial ten