沉淀剂对镍基甲烷化催化剂性能的影响-采矿与安全工程学报-中国.PDFVIP

第40卷 第4期 燃摇 料摇 化摇 学摇 学摇 报 Vol.40 No.4 2012年4 月 Journal of Fuel Chemistry and Technology Apr. 2012 文章编号:0253鄄2409(2012)04鄄0430鄄06 沉淀剂对镍基甲烷化催化剂性能的影响 胡贤辉,王兴军,徐摇 超,于广锁,王辅臣 (华东理工大学 洁净煤技术研究所,上海摇 200237) 摘摇 要:利用尿素、碳酸铵、氨水三种沉淀剂制备了不同的镍基甲烷化催化剂,考察了沉淀条件对催化剂性能的影响。 通过 XRD、H 鄄TPR、BET、TPO等方法对催化剂进行表征。 结果表明,使用不同沉淀剂所得催化剂性能各不相同。 采用尿素沉淀2 2 剂,颗粒的比表面积达到了223.55m / g,具有较稳定的催化活性;碳酸铵沉淀颗粒粒径较大,分散也不够均匀,催化剂更容易 积炭;氨水沉淀制备的催化剂粒径小,与载体结合性强,高温下活性组分易于流失。 分析认为,沉淀剂影响了催化剂前驱体的 形态和结构,造成了分散度、晶相结构、对氢的吸附性质以及抗积炭性等多方面的差异,表现出甲烷化反应活性和稳定性的 不同。 关键词:沉淀剂;制备方法;镍基催化剂;甲烷化反应 中图分类号:O643摇 摇 文献标识码:A Influence of precipitant on the performance of nickel catalyst for methanation HU Xian鄄hui,WANG Xing鄄jun,XU Chao,YU Guang鄄suo,WANG Fu鄄chen (Key Laboratory of Coal Gasification of EducationMinistry of China, East China University of Science and Technology,Shanghai摇 200237,China) Abstract:Ni鄄based catalysts for methanation were prepared by three different precipitants:urea,ammonium carbonate,ammonia and their activities were investigated under different conditions.The characterization of the catalysts were determined by XRD,H 鄄TPR,BET and TPO. Based on the results,the catalysts prepared by 2 different methods of precipitation exhibited different catalytic properties:the surface area of the catalyst prepared 2 by usingureareachedupto223.55m / g,which suggestedan stabilizedcatalyticactivity;thecatalystpreparedby ammonium carbonate precipitant had larger size particles,non鄄uniform distribution and more carbon deposition; the catalyst preparedby ammonia precipitant possessed smaller particle size,stronger interaction with support,but t