复合金属氧化物的制备及其在含酚废水处理中的应用.docVIP

复合金属氧化物的制备及其在苯酚废水处理中的应用 共沉淀法制备℃、(NH4)2CO3为共沉淀剂、陈化时间为4 h、煅烧时间为3 h、活性组分配比为1:1:1；当处理初始浓度为1000 mg/L的模拟苯酚废水时，较适宜的催化氧化工艺条件为：催化剂投加量为0.375 g/L、20 %H2O2投加量为35 mL/L、反应时间为2 h、反应温度为50 ℃。并且在该优化的工艺条件下做了四次重复实验，最终的结果为：苯酚废水的COD平均去除率达到93.77 %，挥发酚的平均去除率达到98.48 %。 关键词：复合金属氧化物；含酚废水；共沉淀法；CWPOPreparation of Composite metal Oxides and Applications on Treatment of Phenol Wastewater ABSTRACT In this paper, the composite transition metal oxide catalysts were synthesized and used to treat the simulative phenol-containing wastewater via the CWPO method. A series of composite metal oxide were prepared by the co-precipitation method on the basis of largely literature consulting. The compositions and morphologies of the obtained products were examined by X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and other modern testing techniques. The catalysts with higher catalytic activities from the as-prepared composite metal oxides were selected to treat the phenol wastewater and then the process conditions of the synthesis and the wastewater treatment were optimized by single factor and orthogonal experiments. The optimized process conditions of the synthesis were obtained as follows: Using (NH4)2CO3 as coprecipitator agent; the aging time is 4 h; the calcination temperature is 600 ℃; the calcination time is 3 h and the ratio of active constituents is 1:1:1. The process conditions of wastewater treatment were optimized as follows: 1000 mg/L for initial phenol concentration of wastewater; 0.0375 g/L for catalyst addition; 35 mL/L for 20 % H2O2 addition; 50 ℃ and 2 h as the treatment temperature and time. Four repeated experiments showed that the average degradation rate of COD and volatile phenol are 93.77 % and 98.48 %, respectively. Key words: Composite metal oxides; Phenol-containing wastewater; Co-precipitation; CWPO目 录 第一章 绪论 1 1.1 复合金属氧化物的制备 1 1.1.1 浸渍法 1 1.1.2 冷冻干燥法 1 1.1.3 水热法 2 1.1.4 溶胶—凝胶法 2 1.1.5 微乳液法 3 1.1.6 共沉淀法 3 1.2 工业废水的处理方法 4 1.2.1 物理法 4 1.2.1.1溶剂萃取法 4 1.2.1.2吸