介孔介晶Ce1-xSmxO2复合材料的合成与催化性能研究.docVIP

介孔介晶Ce1-xSmxO2固溶体的合成及其催化性能研究 马娟宁1,2,3，陈(1江苏大学材料科学与工程学院，镇江 212013；2苏州科技学院江苏省环境功能材料重点实验室，苏州 215011；3苏州科技学院化学与生物工程学院，苏州 215011；4山东大学晶体材料国家重点实验室，济南 250100) P123为模板剂，采用溶剂诱导自组装法(EISA)合成介孔介晶Ce1-xSmxO2固溶体。利用X-射线衍射（XRD）、透射电子显微镜（TEM）、氮气吸脱附技术、化学分析光电子能谱（XPS）等对样品进行了表征。通过PXRD、TEM和BET的结果发现所得样品属于立方萤石结构氧化铈，且平均颗粒尺寸为7.6nm，孔径分布在2.0～3.8 nm m2/g；当掺杂摩尔分数x小于等于0.2时，Ce1-xSmxO2仍为固溶的单一立方相，且孔壁的定向排列未受影响，当x为0.3时，开始出现氧化钐单相，使得孔壁晶粒逐渐向无序取向转化；CO氧化探针反应表明，由于介孔介晶Ce0.7Sm0.3O2比表面积较大，掺杂获得最大的氧缺陷，所以显示了最低的T50值。 通过对材料催化性能检测结果显示Ce0.7Sm0.3O2的催化能力最强，催化速率最快，在35min几乎达到了100%。 关键词 介孔 介晶 氧化铈 脱色 中国分类号：O643.3 文献标识吗：A Synthesis of mesoporous mesocrystal Ce1-xSmxO2 composite materials and Their Catalytic Performance MA Juanning1,2,3 CHEN Zhigang1,2,3,4 QIAN Junchao1,2,3，Gu Cheng1,2,3 (1 Department of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013; 2 Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou, 215009; 3 School of chemistry and biochemistry, Suzhou University of Science and Technology, Suzhou 215011; 4 State Key laboratory of Crystal Material, Shandong University, Jinan, 250100) Abstract Novel mesoporous mesocrystal Ce1-xSmxO2 composite materials have been synthesized via a facile approach of evaporation-induced self-assembly (EISA) in the presence of acetate salt as inorganic species and triblock copolymers P123 as surfactant. The detailed charaterization by power X-ray diffraction(XRD), transmission electron microscope (TEM), selected electron diffraction(SAED) revealed the samples possessing fluorite-structure with the average grain size of ca.7.6 nm. Furthermore, N2 adsorption–desorption measurement illustrated the obtained materials with the two series of pores size in diameter at about 2.0 nm and 3.8 nm and the surface area of 98 m2/g; Doping of Sm2O3 could influence the structure of mesoporous mesocrystal CeO2 if the Sm3+ molor fraction was 0.2 or less, TEM demonstrated that the wall framework consists of