蒸汽爆破和有机溶剂预处理对杨木底物酶水解性质的-林产化学与工业.PDFVIP

蒸汽爆破和有机溶剂预处理对杨木底物 酶水解性质的影响 * 亢 能,刘 忠 ,惠岚峰,卢秀娟,苗 红 (天津科技大学天津市制浆造纸重点实验室, 天津 300457) 摘摇 要:摇 选取三倍体毛白杨为原料,通过分析最优条件下有机溶剂法和蒸汽爆破法预处理后纤维 素得率、结晶度指数、木质素含量及酶水解的结果,比较两种预处理工艺对底物性质的影响。 结果 表明:蒸汽爆破法能脱出部分木质素,而有机溶剂法能使大部分木质素脱除,木质素质量分数比未 KANG Neng摇 摇 处理的降低63.34 %。 与原料相比,经过预处理后,结晶度指数都有所提高,蒸汽爆破预处理后达 1.962,有机溶剂法预处理后达1.712。 有机溶剂法预处理的样品葡萄糖转化率为81.36%,蒸汽爆破预处理的样品的葡 萄糖转化率可达91.29%。 关键词:摇 三倍体毛白杨;有机溶剂法;蒸汽爆破法;纤维素;木质素 中图分类号:TQ35摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 文章编号:0253-2417(2012)04-0043-04 Effect of Steam Explosion and Organosolv Pretreatment on the Hydrolysis of Poplar Substrate KANG Neng,LIU Zhong,HUI Lan鄄feng,LU Xiu鄄juan,MIAO Hong (Tianjin Key Laboratory of Pulp Paper,Tianjin University of Science Technology,Tianjin300457,China) Abstract:The influences of steamexplosionandorganosolvpretreatmentsonthecellulosecontent,crystallinityindex,lignincon鄄 tent and hydrolysis of the triploid populous tomentosa under the optimal conditionswere investigated in present study. Their im鄄 pacts on hydrolysis characterizations of poplar substrate were studied,too. The results indicated that lignin could partly be re鄄 moved by steam explosion pretreatment. In contrast,organosolv pretreatment can removed more lignin than that by steam explo鄄 sion. The lignin was63.34% lower than that of untreated one. The crystallinity index increased to 1.962 after steam explosion and to 1.712 after organosolv pretreatment compared to the raw material. The conversion rate of glucose was 81.36% after or鄄 ganosolv pretreatment and up to91.29% after steam explosion. Key words:triploid chinesewhite poplar;organosolv pretreatment;steam explosion;cellulose;lignin 三倍体毛白杨的纤维素含量比普通毛白杨的高,同时含有更少的木质素,可将其加以利用于燃料乙