N掺杂碳量子点光稳定剂的制备及光学性能.PDFVIP

第37卷摇 第6期 发摇 光摇 学摇 报 Vol郾37 No郾6 2016年6月 CHINESEJOURNAL OF LUMINESCENCE June,2016 文章编号:1000鄄7032(2016)06鄄0655鄄07 N掺杂碳量子点光稳定剂的制备及光学性能 * 王子儒,张光华 ,郭明媛 (陕西科技大学 教育部轻化工助剂化学与技术重点实验室,陕西 西安摇 710021) 摘要:利用水热反应,以柠檬酸为碳源制备碳量子点,再以2,2,6,6鄄四甲基哌啶胺为修饰剂,使碳量子点表 面的含氧基团与2,2,6,6鄄四甲基哌啶胺反应,实现了碳量子点的功能化。 实验结果表明,修饰后的碳量子点 紫外吸收和蓝色荧光发射特性明显优于未修饰的碳量子点。 修饰后的碳量子点平均粒径为3.16 nm,荧光量 子产率为21.2%,水溶性好,颜色浅,可作为高得率浆纸张的光稳定剂使用,并能提高纸张初始白度3ISO% ~ 4ISO%。 随着自由基捕获剂基团的引入,碳量子点能有效捕获纸张因光照而产生的活性自由基,提高了纸张 的耐光性。 关摇 键摇 词:碳量子点;光稳定剂;荧光增白; 自由基捕获剂 中图分类号:O482.31;TQ610.491摇 摇 摇 文献标识码:A摇 摇 摇 DOI:10.3788/ fgx0655 Preparation and Optical Properties of N鄄doped Carbon Dots as Light Stabilizer * WANGZi鄄ru,ZHANG Guang鄄hua ,GUO Ming鄄yuan (Key Laboratory of Auxiliary Chemistry Technologyfor Chemical Industry,Ministry of Education, Shaanxi University of Science Technology,Xi蒺an710021,China) *Corresponding Author,E鄄mail:zhanggh@ Abstract:Novel carbon dotswere successfully synthesized by hydrothermal reactionwith citric acid as carbon source,and 4鄄amino鄄2,2,6,6鄄tetramethylpiperidine was used to react with the oxygen鄄 containing groups on carbon dotssurface. Thismethodwouldoptimizethepropertiesof carbon dots. The modifiedcarbon dotsarebetterthantheunmodifiedcarbon dotsonthecharacteristicsof ultravi鄄 olet absorption and blue fluorescence鄄emission. The modified carbon dots exist in average particle size of 3.16 nm,and have highfluorescence quantumyield of21.2% besidesgoodwater solubility and light color. The results show that the novel