基于主成分和二维差示扫描量热法分析掺假油菜蜜-食品科学.pdfVIP

310 2017, Vol.38, No.14 食品科学 ※安全检测 基于主成分和二维差示扫描量热法 分析掺假油菜蜜 陈桂云，吴 威，陈坤杰* （南京农业大学工学院，江苏南京 210031 ） 摘  要： 30 100 ℃温度范围的差示扫描量热 结合主成分分析和二维相关分析方法深入挖掘掺假油菜蜜在 ～ differential scanning calorimetry DSC （ ， ）曲线，揭示该温度范围掺假对油菜蜜的影响。结果表明，温度微扰下的二 DSC DSC 维 相关谱图和主成分分析结果能相互印证，都能深入揭示原始曲线内含的细节信息。掺假对 分析中热流率 的影响总体是不规则表现。前者在呈现不规则表现的特点上更为直观，后者则能呈现隐藏着的微弱规律。两者结合 DSC 可用来深入分析掺假油菜蜜样本的 特性。 关键词：掺假蜂蜜；差示扫描量热法；主成分分析；二维相关分析 Analysis of Adulterated Oilseed Rape Honey Using Differential Scanning Calorimetry Combined with Principal Component Analysis and Two-Dimensional Correlation Analysis * CHEN Guiyun, WU Wei, CHEN Kunjie (College of Engineering, Nanjing Agricultural University, Nanjing 210031, China) Abstract: Differential scanning calorimetry (DSC) curves of adulterated oilseed rape honey in the temperature range of 30– 100 ℃ were carefully analyzed by principal component analysis (PCA) and two-dimensional (2D) correlation analysis to reveal the effect of adulteration on DSC characteristics of honey. The results showed that 2D-DSC profiles under temperature  perturbation and PCA could support each other and both methods could detect small changes that were difficult to detect in  the original curve. Adulteration affected heat flow rate irregularly by and large. The former method was more intuitive in  showing the irregular characteristics while the latte