SRB对X70钢在土壤模拟溶液中腐蚀行为的影响-科学学研究.PDFVIP

第34 卷 第2 期 中国腐蚀与防护学报 Vol.34 No.2 2014 年4 月 Journal of Chinese Society for Corrosion and Protection Apr. 2014 SRB 对X70 钢在土壤模拟溶液中 腐蚀行为的影响 刘 彤 张艳飞 陈 旭 王 丹 陈 宇 王冠夫 辽宁石油化工大学石油天然气工程学院 抚顺 113001 摘要：采用失重法、SEM、EDS 微观分析方法和电化学阻抗技术研究了X70 钢在有/无SRB 的侵蚀性土壤模拟 溶液中的腐蚀行为。结果表明，在无菌介质中，X70 钢表面生成不具有保护性的腐蚀产物，其腐蚀速率随浸泡 时间的延长而增大；在有菌介质中，钢表面形成致密的生物膜，对界面传质有一定的阻碍作用，从而减轻X70 钢的腐蚀。腐蚀产物的吸附及S 含量随浸泡时间的延长而增加，使得腐蚀产物膜疏松易脱落，促进了基体的腐 蚀。无菌介质中腐蚀产物内层的稳定性与腐蚀产物的沉积及分布有关；而在有菌介质中，多孔的胞外聚合物 对活化过程中的质量传输过程有一定阻碍作用。 关键词：X70 钢 侵蚀性阴离子 SRB 生物膜 腐蚀行为 中图分类号：TG 174 文献标识码：A 文章编号：1005-4537(2014)02-0112-07 Effect of SRB on Corrosion Behavior of X70 Steel in a Simulated Soil Solution LIU Tong, ZHANG Yanfei, CHEN Xu, WANG Dan, CHEN Yu, WANG Guangfu College of Petroleum Engineering, Liaoning Shihua University, Fushun 113001, China Abstract: The corrosion behavior of X70 steel was studied in a simulated soil solution with and without sulfate-reducing bacteria (SRB) by means of weight-loss measurement, SEM-EDS analysis and electrochemical impedance spectroscopy (EIS). The results showed that the corrosion rate in- creased with time in the solution without SRB, while the corrosion product film was loose and non- protective. In the solution with SRB, however, a compact and homogeneous biofilm formed on the steel surface, which could suppress the mass transfer so that to mitigate the steel corrosion, whilst the corrosion product film became loose and apt to spall because of the increasing amount of ab- sorbed substance and sulfide in the corrosion product with time, in consequence the corrosion of