苯胺黑药的厌氧生物降解与机理.pdfVIP

中国环境科学 2016,36(4) ：1033~1038 China Environmental Science 苯胺黑药的厌氧生物降解与机理 * 程亚杰,宋卫锋 ,林丽婷,董 明 (广东工业大学环境科学与工程学院,广东 广州 510006) 摘要： 以苯胺黑药为研究对象,利用 UV 、IC 和 GC-MS 分析苯胺黑药的生物降解途径.结果表明:经 24h 厌氧降解,苯胺黑药降解率达到 44.18%.苯胺黑药厌氧降解不同时段的产物经 IC 及 GC-MS 分析,48h 后产生了 NO3- 、PO43- 、SO42-,苯胺黑药中 P 和 S 部分转化为 PO43- 、 SO 2- .降解过程中检测出苯胺、2,5-二叔丁基苯酚、C H C O 、1-二十醇、十二烷和二十烷.推测其途径为苯胺黑药降解成苯胺及磷酸盐, 4 13 23 l3 2 硫酸盐,苯胺再脱除氨基降解生成 2,5-二叔丁基苯酚,最终降解为链烃类有机物 1-二十醇、二十二烷、二十烷. 关键词：苯胺黑药；厌氧；降解机理 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2016)04-1033-06 * Anaerobic biodegradation and mechanism of aniline aerofloat. CHENG Ya-jie, SONG Wei-feng , LIN Li-ting, DONG Ming (School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China). China Environmental Science, 2016,36(4)：1033~1038 Abstract ：The degradation pathways and mechanisms of aniline aerofloat in an anaerobic reactor were investigated by UV, IC and GC-MS analysis. The results showed that total aniline aerofloat content of up to 44.18% were degraded within 48hours. N, P and S elements in aniline aerofloat were partially converted into NO3-, PO43- and SO42-, respectively, according to IC analysis. The main degradation intermediates were monitored by GC-MS and determined as aniline, 2,5-bis (1,1-dimethylethyl)-, C1 H Cl O , 1-nonadecene, docosane and eicosane. It is proposed that the aniline aerofloat 3 23 3 2 was firstly degraded into aniline, phosphate and sulfate, and was then deaminizated to form phenol, 2,5-bis (1,1-dimethylethyl) and NO3-, which are further