改性污泥腐殖酸的表征及其对Cu2的吸附特性.PDFVIP

中国环境科学 2017,37(3) ：1016~1023 China Environmental Science 改性污泥腐殖酸的表征及其对 Cu2+ 的吸附特性 龙良俊 1,2,王里奥 1*,余纯丽 2,魏星跃 2,卓 琳 2 (1.重庆大学资源及环境科学学院,重庆 400044 ；2.重庆工商 大学环境与资源学院,重庆 400067) 摘要：以城镇污水厂的污泥为原料提取污泥腐殖酸(S-HA),并对其改性得到改性污泥腐殖酸(MS-HA).使用元素分析、扫描电镜(SEM)、傅 里叶红外光谱(FT-IR) X 射线衍射(XRD)和热重-差热扫描量热分析(TG-DSC)对其进行了表征,分析讨论了 MS-HA 的物理化学特性,研究 了 MS-HA 对 Cu2+ 的吸附动力学及等温吸附特性. 结果显示,MS-HA 的 C/N C/H 分别为 5.58 和 6.70,表面疏松并形成非均匀孔,改性 过程发生了脱水和脱羧反应,仍保持无定形结构特征,对 Cu2+ 的吸附平衡时间为 18h,最佳吸附 pH 值为 4～6,不同温度下的吸附过程均符合 准二级动力学模型,吸附等温线符合 Langmuir 模型. 关键词：污泥；腐殖酸；Cu2+ ；吸附 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2017)03-1016-08 Characterization of modified sludge-based humic acid and its adsorption properties for Cu2+ . LONG Liang-jun1,2, 1* 2 2 2 WANG Li-ao , YU Chun-li , WEI Xing-yue , ZHUO Lin (1.College of Resources and Environmental Science, Chongqing University, Chongqing 400044, China；2.College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China). China Environmental Science, 2017,37(3)：1016~1023 Abstract ：Humic acid (S-HA) was extracted from municipal sewage sludge. The S-HA was further modified by heating and the modified humic acid was obtained (MS-HA). The physicochemical properties of the samples were characterized with elemental analysis, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and thermogravimetric-differential scanning calorimetry (TG-DSC). The adsorption kinetics and isothermal adsorption process for copper (II) ions from aqueous solutions was investigated. The results indicated that the C/N and C/H of MS-HA ratio were 5.58 and 6.70, respectively. The surface of MS-HA was loose and abundant with non-homo