燃煤过程中砷的赋存形态及其挥发特性Volatilization-化工学报.PDFVIP

DOI: 10.11949/j.issn.0438-1157 燃煤过程中砷的赋存形态及其挥发特性 邹潺，王春波，郭辉，王贺飞 (华北电力大学能源动力与机械工程学院，河北保定 071003) 摘要：选取3 个国内煤样，利用自制恒温热重装置研究了燃烧过程中砷的赋存特性及其挥发规律。本文通 过测定不同停留时间下燃烧样品中砷的含量，拟合得到砷的挥发曲线和挥发速率曲线，并采用逐级化学提 取的方法对原煤和不同停留时间下的燃烧样品进行形态分析。实验结果表明：温度是影响砷挥发的重要因 素，700-1000℃是砷挥发的主要温度区间。煤粉燃烧过程中，砷的挥发速率与煤粉的失重速率具有同步性； 伴随着煤中水分和挥发分的快速析出，砷也具有较高的挥发速率；随着燃烧过程的深入进行，砷的挥发速 率变得缓慢。煤粉燃烧结束，三种煤（五里庄、红岩和梅花井）砷的挥发比例分别为49.5% 、80.7%、65.0%， 且在燃烧过程中煤中残渣态、硫化物结合态和可交换态砷相互作用迁移。 关键词：煤燃烧；砷的挥发；赋存形态；停留时间；迁移 中图分类号：X511 文献标志码：A 文章编号：0438-1157 （2017 ）00-0000-00 Volatilization characteristics and mode of occurrence of arsenic during coal combustion ZOU Chan, WANG Chunbo, GUO Hui, WANG Hefei (School of Energy, Power Engineering and Mechanical Engineering, North China Electric Power University, Baoding 071003, Hebei Province, China) Abstract: The volatilization characteristics and mode of occurrence of arsenic for three coals were studied by a customized isothermal thermogravimetric experimental system. Limited by online monitoring of gaseous arsenic, the volatilization characteristics of arsenic were determined by measuring the arsenic concentration of ash at the specified residence time in this paper. The volatilization ratio of arsenic at the various residence time was obtained and the volatilization characteristics of arsenic were fitted through B-spline curve. Mode of occurrence of arsenic in the coals and corresponding ashes at the specified residence time was measured by sequential chemical extraction method. The results showed that the volatilization ratio of arsenic increased gradually with temperature, while most arsenic volatilized in 700-1000