基于微量热技术研究钼酸钙纳米饼原位生长的热动力学及机理.pdfVIP

Hans Journal of Nanotechnology 纳米技术, 2017, 7(2), 21-28 Published Online May 2017 in Hans. /journal/nat /10.12677/nat.2017.72003 Based on Microcalor Technology to Research in Situ Growth Thermodynamics and Mechanism of CaMoO4 Nanocake 1 1 1 1 1,2,3* Jiangyuan Qiu , Gaochao Fan , Ting Wan , Biyuan Xiao , Zaiyin Huang 1 College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning Guangxi 2 Key Laboratory of Forest Chemistry and Engineering, Guangxi University for Nationalities, Nanning Guangxi 3 Key Laboratory of Food Safety and Pharmaceutical Analytical Chemistry, Guangxi Colleges and Universities, Nanning Guangxi st th th Received: Apr. 21 , 2017; accepted: May 5 , 2017; published: May 11 , 2017 Abstract In recent years, great progress has been made to investigate the growth process of nanomaterials, and its growth mechanism has also been expanded by various methods. However, there are few methods to acquire the instantaneous thermodynamics information via in situ. In this paper, we use a RD 496-III microcalorimeter with high precision and high sensitivity to obtain the in situ heat flow curves in the growth process of CaMoO4 nanocake. The growth parameters of CaMoO4 nanocake were acquired by thermodynamics equation to investigate the energy and morphology evolution of the CaMoO4 growth mechanism. Results showed that the growth process of CaMoO4 nanocake had gone through two stages, including the phase nucleation and the crystal growth, whose nucleation rate