用原子荧光法测量大米中硒的不确定度评定-中国稻米.pdfVIP

22 5 Vol. 22, No. 5 2007 9 Journal of Inorganic Materials Sep., 2007 : 1000-324X(2007)05-0847-06 ZnS SiO ℄ 2 1 2 ,  ( 1. 2. 430062) ZnS SiO2 Æ SiO @ZnS SiO @ZnS:Mn2+ 2 2 ℄ XRD UV PL TEM SEM AFM ZnS SiO2 ZnS 5% ℄ ZnS; O734 A Preparation of Core-shell SiO /ZnS and Hollow Nanospheres 2 1 2 XU Yang-Zi , HU He (1. Faculty of Physics and Electronic Technology, Hubei University, Wuhan 430062, China; 2. Faculty of Chemistry and Material Science, Hubei University, Wuhan 430062, China) Abstract: SiO2 coated by ZnS nanocrystalline three-dimensional core-shell or hollow nanospheres can be used as building blocks for photonic crystals. To produce these particular three-dimensional nano-materials, a layer-by-layer self-assembled method was used. The electrostatic on the surface of nanometer SiO2 templates could absorb ZnS nanocrystal and form a layer of thickness-controlled shell. The hollow nanospheres were produced by 5% hydrofluoric acid etched the SiO2 templates. The core- shell structure and hollow nanospheres were verified by XRD, UV, PL, TEM, SEM and AFM. The results indicate that after the SiO2 is coated by ZnS nanocrystalline, the core-shell surface is close and neat, and the particle size is homogeneous. The configuration of ZnS hollow nanospheres is intact, and the thick