水溶性导电聚苯胺的制备3.PDF

第 19 卷 第 11 期 化　学　进　展 Vol. 19 No. 11 2007 年 11 月 PROGRESS IN CHEMISTRY 　Nov. , 2007 水溶性导电聚苯胺的制备 陈　卉　马会茹　官建国 (武汉理工大学材料复合新技术国家重点实验室 　武汉 430070) 摘 　要 　水溶性聚苯胺在防腐涂料、电磁屏蔽、生物医学等领域有重要的应用前景。结合本研究组在水 溶性聚苯胺自支撑膜方面的研究进展 ,总结了水溶性聚苯胺的制备方法 ,并重点综述了用嵌段和接枝等共聚 法制备的水溶性聚苯胺及其共聚机理 ,提出水溶性导电聚苯胺今后的研究方向。 关键词 　水溶性聚苯胺 　嵌段共聚 　接枝共聚 　导电高分子 　自支撑膜 ( ) 中图分类号: O631. 5 ; TQ246. 3 ; TN304. 5 　文献标识码 : A 　文章编号 : 1005281X 2007 Preparation of WaterSoluble Conducting Polyanilines Chen Hui 　Ma Huiru 　Guan Jianguo ( State Key Laboratory of Advanced Technology for Materials Synthesis and Processing , Wuhan University of Technology , Wuhan 430070 , China) Abstract 　Watersoluble conducting polyanilines have important potential applications in areas of anticorrosion coatings , electromagnetic shielding , biomedicine etc. Based on the latest literatures and recent works in our research group , the preparation techniques of watersoluble polyaniline are summarized in this paper. The emphasis is focused on the block or graft copolymerization of aniline and watersoluble aniline derivatives as well as the copolymerization mechanisms. The future research directions of the watersoluble polyanilines and the based freestanding membranes are also pointed out. Key words 　watersoluble polyanilines ; block copolymerization ; graft copolymerization ; conducting polymers ; freestanding membranes ( ) 　　聚苯胺 PAn 因其优异的电性能和化学稳定性 导电聚苯胺不仅可以避免环境污染而且会带来更大