磺化芳香族聚脲的制备与表征.PDF

第 3 期 化 　　学 　　世 　　界 　　　　　 1·45 · 磺化芳香族聚脲的制备与表征 李雪莲 , 　林锦鸿 , 　陈大俊 ( 东华大学材料学院 ,纤维材料国家重点实验室 ,上海 200051) ( ) 摘 　要 :采用 4 ,4 ′二苯甲烷二异氰酸酯 MDl 和间苯二胺为单体 ,经两步法溶液聚合制备了芳香族 聚脲。以浓硫酸为磺化试剂对芳香族聚脲膜进行了磺化改性 ,得到一系列不同磺化程度的芳香族 1 聚脲。采用 H NMR 对聚脲样品及磺化改性后样品的化学结构进行了表征。FT IR 分析结果表明 , 芳香族聚脲的磺化程度随磺化时间延长而提高。特性粘度测试表明 ,磺化改性后聚脲样品的特性 粘度随磺化温度的升高及磺化时间的延长而降低。接触角测量表明 ,磺化改性后聚脲样品的表面 亲水性有明显提高。 关键词 :聚脲 ;芳香族 ;磺化 中图分类号:O 632 　　　文献标识码 :A ( ) 文章编号 2006 0314504 Preparation and Characterization of Sulfonated Aromatic Polyureas LI Xuelian , 　LIN Jinghong , 　CHEN Dajun ( State Key Laboratory of Chemical Fibers and Polymer Materials , College of Materials ) Science and Engineering , Donghua University , Shanghai 200051 , China Abstract : Aromatic polyureas were synthesized from 4 ,4′diphenylmethane diisocyanate and mphenylene diamine by two step solution polymerization. A series of sulfonated aromatic polyureas with different sulfonation degrees were 1 prepared. H NMR was employed to characterize the chemical structure of the sulfonated sample. The results of FT IR analysis showed that the sulfonation degree of the aromatic polyureas increased with increasing sulfonation time. The intrinsic viscosity of the sulfonated aromatic polyureas decreased with the increase of sulfonation temperature and sulfonation time. The data of contact angle measurements showed that the surfac