活性炭海绵动态膜生物反应器用于污水处理提标改造中试探究.docVIP

活性炭海绵动态膜生物反应器用于污水处理提标改造中试探究 　　摘要：自行设计研发了以活性炭海绵作为膜基材的动态膜生物反应器，为污水处理的提标排放及资源化利用提供了科学依据及实际参考价值。详细考察了该反应器对污染物的去除效果和运行特性，通过和现有污水处理厂处理效果比较，探索活性炭海绵基材动态膜生物反应器用于城市污水提标改造的可行性。结果表明，在水力停留时间8 h、污泥浓度8 000 mg/L的条件下，活性炭海绵动态膜生物反应器出水COD、NH3-N、TN和TP浓度分别≤35.0 mg/L、≤ 1.4 mg/L、≤10.2 mg/L和≤0.3 mg/L，出水达到《城镇污水处理厂污染物排放标准》 GB189182002一级A标准。活性炭的吸附性能和海绵的空间结构特征协同作用强化了系统对污染物的去除效果，活性炭海绵动态膜生物反应器可完全取代现有污水厂深度处理工艺应用于提标改造。曝气反冲洗可有效减缓出水通量下降，使系统出水通量稳定在30 L/（m2h）左右。 关键词：活性炭海绵；动态膜生物反应器；污水处理；提标改造 中图分类号：X 703.1；Q 503 文献标志码：A 文章编号2014 Abstract：Dynamic membrane bioreactor （DMBR） based on activated carbon sponge materials was studied and developed independently. The pollutant removal efficiency and operational characteristics were investigated in detail， and the feasibility of DMBR application in transformation of real wastewater treatment plant （WWTP） was discussed by comparing the effluents. Results showed that the concentrations of COD， NH3N， TN and TP in effluents were below 35.0 mg/L， 1.4 mg/L， 10.2 mg/L and 0.3 mg/L， respectively， with the HRT of 8 h and MLSS of 8 000 mg/L. The ultimate effluent was qualified to standard A of “Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant” （GB 189182002）. Adsorption of activated carbon and the spatial structure of sponge synergistically strengthen the pollutant removal. DMBR can be used in upgrading and transformation of WWTP by replacing the existing advanced treatment process. The flux of the DMBR was recovered by intensified aeration backwashing and maintained steadily at the level of 30 L/（m2h）. Key words：Activated carbon sponge； Dynamic membrane bioreactor； Wastewater treatment； Upgrading and reconstruction 膜生物反应器（Membrane bioreactor， MBR）因其出水水质好、剩余污泥少、占地面积省在污水深度处理及提标改造中日益得到广泛关注和推广[17]，但膜材料价格和膜污染仍然是限制该技术大范围应用的瓶颈[810]。为解决传统MBR的不足，动态膜生物反应器（Dynamic membrane bioreactor， DMBR）应运而生。DMBR是建立在传统MBR基础之上的新型生物反应器，以无纺布、筛网等粗孔材料为膜基材，通过活性污泥过滤过程中形成的生物动态膜实现近似于微滤膜的过滤效果，该技术具有基建及运行费用低、膜污染易控制等优点[1112]。Seo等[13]、Hong[14]等研究发