储氢材料课件（英文）-1.ppt

4) V-Ti-Cr system－M. Okada, E. Akiba, L.X. Chen et al. As Ti/Cr = ~0.75, the alloys have high capacity ; Ⅲ. V-based alloys for gaseous application Relation between the hydrogen storage capacity and the Ti/Cr ratio Ⅲ. V-based alloys for gaseous application As ↑ V content, → activation ↓, Cabs ↑ and Cdes reaches the highest at 50 at.% ; Low hydrogen desorption efficiency: － maximum Cabs= 2.7~3.6 wt.%; maximum Cdes≤~2.4 wt.%; Commonly alloying with Zr, Mn and Fe etc. 5) V-Ti-Cr-M (M = Mn, Fe ……) system － M. Okada, S.W. Cho, L.X. Chen et al. + Mn : hysteresis↓, and effective Cdes first↑than↓, but activation and absorbing capacity↓; + Fe : homosphere↑, cycling life↑, cell volume↓, Peq↑, but absorbing capacity↓. Ⅲ. V-based alloys for gaseous application 5) V-Ti-Cr-Zr system － S.W. Cho, L.X. Chen et al. Hysteresis↓; Ⅲ. V-based alloys for gaseous application Activation↑, but plateau slope↑due to the formation of ZrCr2 secondary phase; Absorbing capacity↓due to ZrCr2 phase; As Ti/Cr ? 0.70, the formation of ZrCr2 is restrained ; Adding a small quantity of Zr, such as annealed V57Ti16Zr5Cr22 can acquire the highest Cabs= 3.55 wt.% and Cdes= 2.14 wt.% Ⅲ. V-based alloys for gaseous application 6) V + x wt%TiFe0.85Mn0.15 (x=50,60,70)－C.P. Chen et al. As x = 60, activation behavior ↑, good P-C-T characteristic and over-all properties; Ⅲ. V-based alloys for gaseous application 1) Heat treatment 3.2 The effects of preparation technics high temperature annealing and rapid cooling (water cooling) → ↑effective desorbing capacity Ⅲ. V-based alloys for gaseous application such as: heated at 1573K×1min and water cooling f or V35Ti25Cr40 ; heated at 1473K×8hrs and water cooling for V57Ti16Zr5Cr22 . 2) Mechanical ball-milling such as: [ V or V-based alloys + (Ti, Ni, LaNi5, etc) ] prepared by ball-milling activation↑; Ⅲ. V-based alloys for gaseous applicatio