高强度明胶-阿拉伯胶电泳显示微胶囊的制备-高校化学工程学报.PDFVIP

第 26 卷第 4 期 高 校 化 学 工 程 学 报 No.4 Vol.26 2012 年 8 月 Journal of Chemical Engineering of Chinese Universities Aug. 2012 文章编号：1003-9015(2012)04-0654-07 网络出版地址：/kcms/detail/33. 1141.TQ1629.005.html 高强度明胶-阿拉伯胶电泳显示微胶囊的制备  张 静, 李祥高, 王世荣 (天津大学 化工学院, 天津 300072) 摘 要：以球磨法制备的炭黑、TiO2 的四氯乙烯电泳分散体系为囊芯，以明胶、阿拉伯胶为壁材，采用复凝聚法制备 了电泳微胶囊。详细研究了壁材比，反应温度、表面活性剂浓度、pH 的控制、固化条件等因素对微胶囊性能的影响， 并采用落球冲击实验对微胶囊强度进行了表征。结果表明，微胶囊制备的优化条件为明胶与阿拉伯胶用量比为 1:1(w:w)，反应温度50℃，十二烷基硫酸钠(SDS)浓度0.001 gmL1，醋酸浓度5.0% ~7.5%，戊二醛浓度10% ~15%。 囊壁固化条件是在pH = 4.5~4.8 、5℃时固化1 h 后，然后在pH = 8~11 、50℃时再固化70 min 。在此条件下制备的微胶 囊机械强度高且表面光滑，粒径分布在30~80 μm ，产率高于90% 。用微胶囊制备的显示器件具有良好的显示效果，反 射率达到45%~56% ，对比度为5~7，响应时间为190~400 ms。 关键词：电泳显示；微胶囊；明胶；阿拉伯胶；复凝聚 中图分类号： O 636 文献标识码：A Preparation of High-Strength Gelatin-Acacia Microcapsules Used for Electrophoretic Display ZHANG Jing, LI Xiang-gao, WANG Shi-rong (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China) Abstract: The electrophoretic microcapsules containing carbon black and TiO2 particles dispersed in tetrachloroethylene (TCE) were prepared by complex coacervation between gelatin and acacia, and the carbon black and TiO2 particles in it were prepared by ball milling. Various factors affecting the properties of the prepared microcapsules, such as the ratio of gelatin to acacia, temperature of the reaction system, concentration of surfactant, pH value and curing process, were experimentally investigated. Meanwhile, the mechanical strength of the prepared m