硫化氢对遇水膨胀橡胶性能影响.pdfVIP

学兔兔 全国中文核心期刊 新 巍 硫化氢对遇水膨胀橡胶性能的影晌 杨盛华，余剑英，黄永方 (武汉理工大学材料学院，湖北武汉 430070) 摘要：研究了不同浓度的I-I~S气体及其溶液对遇水膨胀橡胶(WSR)质量变化、力学性能和体积膨胀倍率的影响。结果表明，在 不同浓度的H：S气体和H2S溶液中，WSR的拉伸强度、扯断伸长率和体积膨胀倍率均有较大程度降低，腐蚀时间越长、浓度越大，降 低程度越大，但腐蚀时间达到20d时，不同浓度的H2S气体或H 溶液对WsR性能的影响差异明显减小。此外，在I-I~S气体中， WSR的质量逐渐增大，而在H2s溶液中，WSR的质量逐渐减小，但其质量损失率呈现先增加后减小的变化趋势。 关键词：遇水膨胀橡胶；硫化氢；腐蚀：密封材料 中图分类号：TU57 8 文献标识码：B 文章编号：1001—702X(2010)O1—0066—04 Effect of hydrogen sulfide on the performance of water swelling rubber YANG Shenghua，YU Jianying，HUANG Yortgfang (School of Material Science and Engineering，Wuhan University of Technology，Wuhan 430070 Hubei，China) Abstract：Effects of the concentrations of H2s gas and H2s solution on weight chan~ng，mechanical properties and volume expansion ratio of water swelling rubber(WSR)were investigated．The results showed that the tensile strength，elongation at break and volume expansion ratio of WSR markedly decrease after being corroded by both H2S gas and H2S solution of different concentrations，and the dropping degree became bigger with the increments of the concentration and corrosion time．However，when the eolTosion time reached 20 d，the effects of the concentrations of H2S gas or H2S solution on the mechanical properties and volume expansion ratio of WSR don1 have significant difference．In addition，the weight of WSR increased with time in H2S gas， whereas the weight of WSR reduced with time in H2s solution，but the mass loss rate increased first and then showed decreasing trends．