凝胶热处理方式对Fe-TiO2薄膜表面形态和亲水性能影响.pdf

学兔兔 化 工 进 展 ·l134· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第7期 凝胶热处理方式对Fe．TiO2薄膜表面形态及亲水性能的影响 张 锋，董如林，马 丽，陈智栋 (江苏工业学院化工系，江苏 常州 213164) 摘 要：实验采用溶胶一凝胶法，以聚乙二醇(PEG)为致孔剂制备了仿生的Fe3+掺杂TiO2(Fe．TiO2)多孔薄膜。 应用TG—DSC分析了凝胶薄膜的热分解行为，采用SEM、XRD及接触角测定仪等分析测试手段分别考察了两种 热处理方式对形成薄膜的表面形态、相态以及亲水性的影响。结果表明：由恒温方式处理得到的薄膜连续无裂纹， 其表面形成了分布均匀的、直径2～5 lam的球面形气孔，而升温方式得到的薄膜其表面形成了分布均匀的、直径 约100 gm的葵花状斑块；溶胶不经陈化得到的薄膜为无定形，而经80℃、8 h陈化后制备的薄膜为锐钛型；采 用Fe。 掺杂及在薄膜表面形成气孔，能显著提高TiO2薄膜的亲水性，并且恒温热处理方式得到的薄膜其亲水性优 于升温方式得到的薄膜样品。 关键词：热处理方式；表面形态；Fe—TiO2多孔薄膜；聚乙二醇；亲水性 中图分类号：O484．4 文献标识码：A 文章编号：1000—6613(2009)07—1134—05 Effect of gel heat—treatment regime on morphology and hydrophilicity of Fe-Ti02 thin film ZHANG Feng，DONG Rulin，MA Li，CHENZhidong (Department ofChemical Engineering，Jiangsu Polytechnic University，Changzhou 213164，Jiangsu，China) Abstract：Biomimetic Fe—Zi02 films were prepared by the sol gel method using polyethylene glycol (PEG)as a pore direction agent．The thermal decomposition behavior of the gel film was analyzed by TG—DSC．The effect of the gel heat—treatment regime on the morphology，phase and hydrophilicity of the film was investigated by scanning electron microscope，X—ray diffraction and contact goniometer， respectively．The results showed that a constant temperature regime produced a continuous film with well—distributed 2— 5 gm spherical pores，while a temperature programming regime formed a well—distributed about l OOgm sunflower-like spots on the film surface．Amorphous and anatase films could b