射出压缩成型燃料电池双极板导电品质之研究李平惠机械工程系.PDFVIP

教專研 98P-17 射出壓縮成型燃料電池雙極板導電品質之研究 射出壓縮成型燃料電池雙極板導電品質之研究 李平惠 機械工程系 摘要 燃料電池(Fuel Cell)是一種對地球生態污染性較低且發電效率較高的能源，而雙極板 (Bipolar Plate)佔據全部電池大半主體，是燃料電池的 主要元件。以高分子導電性複合材 料成型之雙極板，具有重量輕 、抗腐蝕佳、成本低、加工快的優點，若能於導電度上有 所突破，就能逐漸取代石墨或金屬 雙極板。本研究選取聚酚硫 (PPS)+50wt.%碳纖維 (CF) 高分子導電性複合材料，藉由改變射出成型製程參數（模 溫、料溫、射出速度與保壓壓 力），探討射出成型製作無流道平板製程中，對碳纖維配向、分佈與導電性之影響。 研究結果顯示，射出成型較佳化製程參數為：模溫 210℃、料溫330℃、射速60mm/s 、 保壓 150MPa ，雙極板平面導電度為81S/cm ，接近DOE國際之標準，達到本研究目的之 關鍵要求。 關鍵字： 雙極板、碳纖維、配向 Abstract Fuel cells constitute one of the most promising sources of clean energy and bipolar plate is an important component of a fuel cell. Electrically conductive polymer composites for molding of bipolar plates, has the advantages of lightweight, low cost, chemical stability, and ease of fabrication. They will can alternative to graphite and metal-based material if one can improve the conductivity of polymer composite. In this study, bipolar plates without channel were injection molding (IM) using PPS polymer filled with 50 wt% carbon fiber under different molding parameters was addressed. The effect of processing parameters including mold temperature, melt temperature, injection velocity, and packing pressure on the electrical conductivity performance were analyzed and correlated. Meanwhile, influence of fiber orientation and distribution from molding conditions was evaluated. The results showed when the better molding condition was chosen (mold temperature 210℃, melt temperature 330℃, injection velocity 60mm/s, and packing pressure 150MPa) for IM. The in-plane conductivity can reached 81S/cm and it has be close to the DOE target. Keyword: bipolar plate, carbon fiber